Email this article Radiation-chemical synthesis of tetrafluoroethylene telomeres in dimethyl carbonate and dimethoxyethane
- Authors: Kichigina G.A.1, Kushch P.P.1, Baimuratova G.R.1, Slesarenko N.A.1, Kraevaya O.A.1, Yarmolenko O.V.1, Kiryukhin D.P.1
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Affiliations:
- Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the RAS
- Issue: Vol 59, No 4 (2025)
- Pages: 268–273
- Section: RADIATION CHEMISTRY
- URL: https://cardiosomatics.ru/0023-1193/article/view/687751
- DOI: https://doi.org/10.31857/S0023119325040112
- EDN: https://elibrary.ru/aylozr
- ID: 687751
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Abstract
The kinetics of radiation-induced telomerization of tetrafluoroethylene in dimethyl carbonate and dimethoxyethane was studied, new tetrafluoroethylene telomers were obtained. A detailed study of the IR spectra confirms the fact that fragments of solvent molecules are included in the composition of the obtained telomers. Selection of synthesis parameters (tetrafluoroethylene concentration, radiation dose) allows obtaining telomer solutions with the necessary characteristics for their further use as an additive in electrolytes for lithium-ion batteries.
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About the authors
G. A. Kichigina
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the RAS
Author for correspondence.
Email: kga@icp.ac.ru
Russian Federation, Chernogolovka
P. P. Kushch
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the RAS
Email: kga@icp.ac.ru
Russian Federation, Chernogolovka
G. R. Baimuratova
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the RAS
Email: kga@icp.ac.ru
Russian Federation, Chernogolovka
N. A. Slesarenko
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the RAS
Email: kga@icp.ac.ru
Russian Federation, Chernogolovka
O. A. Kraevaya
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the RAS
Email: kga@icp.ac.ru
Russian Federation, Chernogolovka
O. V. Yarmolenko
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the RAS
Email: kga@icp.ac.ru
Russian Federation, Chernogolovka
D. P. Kiryukhin
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the RAS
Email: kga@icp.ac.ru
Russian Federation, Chernogolovka
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