Synthesis, crystal structure and spectroscopic study of lead monochloroacetate, Pb(ClCH2COO)2

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Crystals of lead monochloroacetate, Pb(ClCH2COO)2, were obtained in the reaction of lead carbonate and aqueous chloroacetic acid. The compound crystallizes in the monoclinic symmetry (space group P21/c) with the unit cell parameters: a = 10.8346(6), b = 7.7239(4), c = 10.1484(5) Å, β = 106.542(5)°. Like other medium- and long-chain lead carboxylates, the crystal structure of lead monochloroacetate is layered. Lead atoms are located in distorted seven-vertex PbO7-polyhedra which share edges and form layers. Features of the crystal structures of lead salts of carboxylic acids with unbranched hydrocarbon radicals are discussed. In particular, salts of lead(II) n-alkyl carboxylates with the general formula Pb(CnH2n+1COO)2, despite belonging to different symmetry and space groups (monoclinic P21/m for n = 2 and 3, triclinic P1 for n = 4–9, and monoclinic P21/c for Pb(ClCH2COO)2), are characterized by the same arrangement of molecules, so they can be considered structurally related.

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作者简介

S. Ivanov

Lomonosov Moscow State University; FRC Kola Science Centre RAS

Email: aks.crys@gmail.com

Faculty of Chemistry, Lomonosov Moscow State University; Laboratory of Arctic Mineralogy and Material Sciences, FRC Kola Science Centre RAS

俄罗斯联邦, 1-3 Leninskie Gory, Moscow 119991; 14 Fersman str., Apatity 184209

A. Banaru

Lomonosov Moscow State University; FRC Kola Science Centre RAS

Email: aks.crys@gmail.com

Faculty of Chemistry, Lomonosov Moscow State University; Laboratory of Arctic Mineralogy and Material Sciences, FRC Kola Science Centre RAS

俄罗斯联邦, 1-3 Leninskie Gory, Moscow 119991; 14 Fersman str., Apatity 184209

V. Kireev

FRC Kola Science Centre RAS

Email: aks.crys@gmail.com

Laboratory of Arctic Mineralogy and Material Sciences

俄罗斯联邦, 14 Fersman str., Apatity 184209

D. Charkin

Lomonosov Moscow State University; FRC Kola Science Centre RAS

Email: aks.crys@gmail.com

Faculty of Chemistry, Lomonosov Moscow State University; Laboratory of Arctic Mineralogy and Material Sciences, FRC Kola Science Centre RAS

俄罗斯联邦, 1-3 Leninskie Gory, Moscow 119991; 14 Fersman str., Apatity 184209

A. Kompanchenko

FRC Kola Science Centre RAS

Email: aks.crys@gmail.com

Geological Institute

俄罗斯联邦, 14 Fersman str., Apatity 184209

A. Gosteva

FRC Kola Science Centre RAS; Federal State Autonomous Educational Institution of Higher Education “Murmansk Arctic University”

Email: aks.crys@gmail.com

I.V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, FRC Kola Science Centre RAS

俄罗斯联邦, 26a, Akademgorodok, Apatity 184209; 15 Kapitana Egorova str., Murmansk 183038

S. Aksenov

FRC Kola Science Centre RAS

编辑信件的主要联系方式.
Email: aks.crys@gmail.com

Laboratory of Arctic Mineralogy and Material Sciences; Geological Institute

俄罗斯联邦, 14 Fersman str., Apatity 184209

参考

  1. Krivovichev S.V., Mentre O., Siidra O.I. et al. // Chem. Rev. 2013. V. 113. № 8. P. 6459. https://doi.org/10.1021/cr3004696
  2. Persson I., Lyczko K., Lundberg D. et al. // Inorg. Chem. 2011. V. 50. № 3. P. 1058. https://doi.org/10.1021/ic1017714
  3. Siidra O.I., Krivovichev S.V., Filatov S.K. // Z. Krist. 2008. V. 223. № 1–2. P. 114. https://doi.org/10.1524/zkri.2008.0009
  4. Matar S.F., Galy J. // Prog. Solid State Chem. 2015. V. 43. № 3. P. 82. https://doi.org/10.1016/j.progsolidstchem.2015.05.001
  5. Fiuza-Maneiro N., Sun K., López-Fernández I. et al. // ACS Energy Lett. 2023. V. 8. № 2. P. 1152. https://doi.org/10.1021/acsenergylett.2c02363
  6. Zhao Y., Zhu K. // Chem. Soc. Rev. 2016. V. 45. № 3. P. 655. https://doi.org/10.1039/C4CS00458B
  7. Stoumpos C.C., Malliakas C.D., Kanatzidis M.G. // Inorg. Chem. 2013. V. 52. № 15. P. 9019. https://doi.org/10.1021/ic401215x
  8. Tangboriboon N., Pakdeewanishsukho K., Jamieson A. et al. // Mater. Chem. Phys. 2006. V. 98. № 1. P. 138. https://doi.org/10.1016/j.matchemphys.2005.09.034
  9. Jachuła J., Kołodyńska D., Hubicki Z. // Can. J. Chem. 2010. V. 88. № 6. P. 540. https://doi.org/10.1139/V10-027
  10. Shahid M., Pinelli E., Dumat C. // J. Hazard. Mater. 2012. V. 219–220. P. 1. https://doi.org/10.1016/j.jhazmat.2012.01.060
  11. Hu M.-L., Morsali A., Aboutorabi L. // Coord. Chem. Rev. 2011. V. 255. № 23–24. P. 2821. https://doi.org/10.1016/j.ccr.2011.05.019
  12. Martínez-Casado F.J., Ramos-Riesco M., Rodríguez-Cheda J.A. et al. // J. Mater. Chem. C. 2014. V. 2. № 44. P. 9489. https://doi.org/10.1039/C4TC01645A
  13. Martínez-Casado. F.J., Ramos-Riesco M., Rodríguez-Cheda J.A. et al. // Phys. Chem. Chem. Phys. 2017. V. 19. № 26. P. 17009. https://doi.org/10.1039/C7CP02351K
  14. Warrier A.V.R., Narayanan P.S. // Spectrochim. Acta. A. 1967. V. 23. № 4. P. 1061. https://doi.org/10.1016/0584-8539(67)80029-1
  15. Filipović I., Bujak A., Vukičević V. // Croat. Chem. Acta. 1970. V. 42. № 3. P. 493.
  16. Oxford Diffraction. CrysAlisPro. Oxford Diffraction Ltd, Abingdon, Oxfordshire, UK. 2009.
  17. Palatinus L., Chapuis G. // J. Appl. Cryst. 2007. V. 40. № 4. P. 786. https://doi.org/10.1107/S0021889807029238
  18. Petricek V., Dusek M., Palatinus L. // Z. Krist. 2014. V. 229. № 5. P. 345. https://doi.org/ 10.1515/zkri-2014-1737
  19. Petříček V., Palatinus L., Plášil J., Dušek M. // Z. Krist. 2023. V. 238. № 7–8. P. 271. https://doi.org/10.1515/zkri-2023-0005
  20. Spinner E. // J. Chem. Soc. 1964. P. 4217. https://doi.org/10.1039/jr9640004217
  21. Bernard M.-C., Costa V., Joiret S. // e-Preservation Sci. 2009. V. 6. P. 101.
  22. Teixeira-Dias J.J.C., Fausto R. // Pure Appl. Chem. 1989. V. 61. № 5. P. 959. https://doi.org/10.1351/pac198961050959
  23. Katon J.E., Sinha D. // Spectrochim. Acta. A. 1977. V. 33. № 1. P. 45. https://doi.org/10.1016/0584-8539(77)80146-3
  24. Jassem N.A., El-Bermani M.F. // Spectrochim. Acta. A. 2010. V. 76. № 2. P. 213. https://doi.org/10.1016/j.saa.2010.03.022
  25. Hermans J.J., Keune K., van Loon A., Iedema P.D. // J. Anal. At. Spectrom. 2015. V. 30. № 7. P. 1600. https://doi.org/10.1039/C5JA00120J
  26. Shi Q., Cao R., Hong M.C. et al. // Transit. Met. Chem. 2001. V. 26. P. 657. https://doi.org/10.1023/A:1012008427788
  27. Mido Y., Kawashita T., Suzuki K. et al. // J. Mol. Struct. 1987. V. 162. № 3–4. P. 169. https://doi.org/10.1016/0022-2860(87)87050-3
  28. Blatov V.A., Shevchenko A.P., Proserpio D.M. // Cryst. Growth Des. 2014. V. 14. № 7. P. 3576. https://doi.org/10.1021/cg500498k
  29. Shevchenko A.P., Shabalin A.A., Karpukhin I.Y., Blatov V.A. // Sci. Technol. Adv. Mater. Methods. 2022. V. 2. № 1. P. 250. https://doi.org/10.1080/27660400.2022.2088041
  30. Alexandrov E.V., Blatov V.A., Kochetkov A.V., Proserpio D.M. // CrystEngComm. 2011. V. 13. № 12. P. 3947. https://doi.org/10.1039/c0ce00636j
  31. Martínez-Casado F.J., Ramos-Riesco M., Rodríguez-Cheda J.A. et al. // Inorg. Chem. 2016. V. 55. № 17. P. 8576. https://doi.org/10.1021/acs.inorgchem.6b01116
  32. O’Keeffe M., Peskov M.A., Ramsden S.J., Yaghi O.M. // Acc. Chem. Res. 2008. V. 41. № 12. P. 1782. https://doi.org/10.1021/ar800124u
  33. Delgado-Friedrichs O., O’Keeffe M. // Acta Cryst. A. 2003. V. 59. № 4. P. 351. https://doi.org/10.1107/S0108767303012017
  34. Krivovichev S.V. // Angew. Chem. Int. Ed. 2014. V. 53. № 3. P. 654. https://doi.org/10.1002/anie.201304374
  35. Krivovichev S.V. // CrystEngComm. 2024. V. 26. № 9. P. 1245. https://doi.org/10.1039/D3CE01230A

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2. Fig. 1. Raman spectrum of lead monochloroacetate Pb(ClCH2COO)2. Regions (a) and (b) are highlighted in the overall spectrum (c).

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3. Fig. 2. IR spectrum of lead monochloroacetate Pb(ClCH2COO)2.

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4. Fig. 3. General view of the crystal structure of the compound Pb(ClCH2COO)2 (a) and structural features of the electrically neutral layer {Pb(ClCH2COO)2} (b).

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5. Fig. 4. Coordination environment of the Pb2+ cation in the crystal structure of Pb(ClCH2COO)2.

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6. Fig. 5. Networks kgd (a) and sdf (b) in RCSR [27].

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7. Fig. 6. The 3,4,7L7 network in its most symmetrical implementation on a plane. Black circles correspond to relaxed cation positions, gray circles to anion positions.

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