Crystal structure of new iodacetatouranylates R[UO2(CH2ICOO)3]2∙2CH2ICOOH∙4H2O (R = Sr or Ba)

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅或者付费存取

详细

Synthesis, IR spectroscopic, and X-ray diffraction studies of R[UO2(mia)3]2·2Hmia·4H2O crystals, where R = Sr2+ (I) or Ba2+ (II), and mia is the monoiodoacetate ion CH2ICOO−, have been carried out. The [UO2(mia)3]– complexes correspond to the crystal chemical formula A(B01)3, where A = UO 22 +, B01 = mia. It has been established that a common feature of I and II is the presence of trinuclear electrically neutral clusters {R[UO2(mia)3]2(Hmia)2(H2O)2}. At the centers of the clusters there are trigonal RO8 dodecahedra; half of their oxygen atoms belong to four different mia anions of two [UO2(mia)3]– complexes. In addition, each R atom coordinates the oxygen atoms of two water molecules and the carbonyl oxygen atoms of two Hmia molecules. Using the method of molecular Voronoi–Dirichlet polyhedra, an analysis of noncovalent interactions in the structure of I was carried out.

全文:

受限制的访问

作者简介

L. Serezhkina

Samara National Research University

编辑信件的主要联系方式.
Email: lserezh@samsu.ru
俄罗斯联邦, Samara 443011

M. Grigoriev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: lserezh@samsu.ru
俄罗斯联邦, Moscow, 119071

D. Mitinа

Samara National Research University

Email: lserezh@samsu.ru
俄罗斯联邦, Samara 443011

V. Serezhkin

Samara National Research University

Email: lserezh@samsu.ru
俄罗斯联邦, Samara 443011

参考

  1. Loiseau T., Mihalcea I., Henry N., Volkringer C. // Coord. Chem. Rev. 2014. Vol. 266. P. 69.
  2. Lermontov A.S., Lermontova E.K., Wang Y.Y. // Inorg. Chim. Acta. 2009. Vol. 362. P. 3751.
  3. Ramos Silva M., Matos Beja A., Paixao J.A., Alte da Veiga L., Martin-Gil J. // Acta Crystallogr., Sect. C. 1999. Vol. 55. P. 2039.
  4. Zachariasen W.H., Plettinger H.A. // Acta Crystallogr. 1959. Vol. 12. P. 526.
  5. Zalkin A., Ruben H., Templeton D.H. // Acta Crystallogr., Sect. B. 1982. Vol. 38. P. 610.
  6. Anisimova N., Hoppe R., Serafin M. // Z. Anorg. Allg. Chem. 1997. Vol. 623. P. 35.
  7. Savchenkov A.V., Klepov V.V., Vologzhanina A.V., Serezhkina L.B., Pushkin D.V., Serezhkin V.N. // CrystEngComm. 2015. Vol. 17. P. 740.
  8. Serezhkin V.N., Grigoriev M.S., Abdulmyanov A.R., Fedoseev A.M., Savchenkov A.V., Stefanovich S.Yu., Serezhkina L.B. // Inorg. Chem. 2017. Vol. 56. P. 7151.
  9. Клепов В.В., Вологжанина А.В., Сережкина Л.Б., Сережкин В.Н. // Радиохимия. 2012. Т. 54. № 6. С. 500. https://doi.org/10.1134/S1066362213010074 (Klepov V.V., Vologzhanina A.V., Serezhkina L.B., Serezhkin V.N. // Radiochemistry. 2013. Vol. 55. № 1. P. 36.).
  10. Klepov V.V., Peresypkina E.V., Serezhkina L.B., Karasev M.O., Virovets A.V., Serezhkin V.N. // Polyhedron. 2013. Vol. 61. P. 137.
  11. Katon J.E., Carll T.P. // J. Mol. Struct. 1971. Vol. 7. P. 391.
  12. Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. Wiley, 2009. Parts A, B.
  13. SAINT-Plus (Version 7.68). Madison, Wisconsin (USA): Bruker AXS, 2007.
  14. Sheldrick G.M. TWINABS. Madison, Wisconsin (USA): Bruker AXS, 2012.
  15. Krause L., Herbst-Irmer R., Sheldrick G.M., Stalke D. // J. Appl. Crystallogr. 2015. Vol. 48. Part 1. P. 3.
  16. Sheldrick G.M. // Acta Crystallogr., Sect. A. 2008. Vol. 64. N 1. P. 112. https://doi.org/10.1107/S0108767307043930
  17. Sheldrick G.M. // Acta Crystallogr., Sect. C. 2015. Vol. 71. N 1. P. 3. https://doi.org/10.1107/S2053229614024218
  18. Cережкин В.Н., Михайлов Ю.Н., Буслаев Ю.А. // ЖНХ. 1997. Т. 42. № 12. С. 2036.
  19. Serezhkin V.N., Vologzhanina A.V., Serezhkina L.B., Smirnova E.S., Grachova E.V., Ostrova P.V., Antipin M.Yu. // Acta Crystallogr., Sect. B. 2009. Vol. 65. N 1. P. 45.
  20. Serezhkin V.N., Savchenkov A.V., Pushkin D.V., Serezhkina L.B. // Appl. Solid State Chem. 2018. N 2. P. 2. https://doi.org/10.18572/2619-0141-2018-2-3-2-16
  21. Serezhkin V.N., Yu L., Savchenkov A.V. // Cryst. Growth Des. 2022. Vol. 22. N 11. P. 6717. https://doi.org/10.1021/acs.cgd.2c00884
  22. Сережкина Л.Б., Митина Д.С., Вологжанина А.В., Григорьев М.С., Пушкин Д. В., Сережкин В.Н. // ЖНХ. 2022. Т. 67. № 11. С. 1581. (Serezhkina L.B., Mitina D.S., Vologzhanina A.V., Grigoriev M.S., Pushkin D.V., Serezhkin V.N. // Russ. J. Inorg. Chem. 2022. Vol. 67. P. 1769. https://doi.org/10.1134/S0036023622600915).
  23. Desiraju G.R., Ho P.S., Kloo L., Legon A.C., Marquardt R., Metrangolo P., Politzer P., Resnati G, Rissanen K. // Pure Appl. Chem. 2013. Vol. 85. N 8. P. 1711. http://dx.doi.org/10.1351/PAC-REC-12-05-10
  24. Cavallo G., Metrangolo P., Milani R., Pilati T., Priimagi A., Resnati G., Terraneo G. // Chem. Rev. 2016. Vol. 116. P. 2478. https://doi.org/10.1021/acs.chemrev.5b00484

补充文件

附件文件
动作
1. JATS XML
下载
2. Fig. 1. Structure of the trinuclear cluster {Sr[UO2(mia)3]2 (Hmia)2(H2O)2}. To simplify the figure, the H atoms are not shown. For the right U(VI) atom in the cluster, the CP (hexagonal bipyramid) is shown, and for the left one, the corresponding VDP (hexagonal prism).

下载 (78KB)
索引源数据
3. Fig. 2. Structure of the trinuclear cluster {Ba[UO2(mia)3]2 (Hmia)2(H2O)2}. To simplify the figure, the H atoms are not shown. For the right U(VI) atom in the cluster, the CP (hexagonal bipyramid) is shown, and for the left one, the corresponding VDP (hexagonal prism).

下载 (72KB)
索引源数据

版权所有 © Russian Academy of Sciences, 2024