Determination of pesticide residues in wheat grain by the GC-MS/MS method after their isolation using the modified quechers method and hyper cross-linked polystyrene at the purification stage

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

Hyper cross-linked polystyrene was proposed for purification of extracts after sample preparation by QuEChERS method using multicomponent dispersive solid-phase extraction for determination of 19 pesticide residues in wheat grain by gas chromatography with tandem mass spectrometric detection. Sample preparation included extraction with water and acetonitrile and further purification of the extracts using hyper cross-linked polystyrene. The method provided quantitative separation of pesticides (degrees of separation ranged from 66 to 100 %). Pesticides were identified by selected transitions in multiple reaction monitoring mode. Determination was carried out by matrix graduation method and the limits of detection and determination were 0.03–0.3 and 0.1–1.0 µg/kg, respectively. The analysis of contaminated wheat samples showed that the results satisfactorily coincide with the data obtained by the classical QuEChERS method for determination of pesticide residues in agricultural products.

Толық мәтін

Рұқсат жабық

Авторлар туралы

Е. Osinova

Federal Center for Animal Health; D.I. Mendeleev Russian University of Chemical Technology

Email: artem150196@mail.ru
Ресей, Yurievets mkr., Vladimir 6009101; Miusskaya Pl., 9, Moscow 125047

A. Melekhin

Federal Center for Animal Health

Хат алмасуға жауапты Автор.
Email: artem150196@mail.ru
Ресей, Yurievets mkr., Vladimir 6009101

D. Bulkatov

Federal Center for Animal Health

Email: artem150196@mail.ru
Ресей, Yurievets mkr., Vladimir 6009101

V. Tishchenko

Federal Center for Animal Health; Peoples' Friendship University of Russia

Email: artem150196@mail.ru
Ресей, Yurievets mkr., Vladimir 6009101; Miklukho-Maklaya St., 6, Moscow, 117198

I. Khalyavin

Federal Center for Animal Health

Email: artem150196@mail.ru
Ресей, Yurievets mkr., Vladimir 6009101

Әдебиет тізімі

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2. Ris. 1. Stepeni vydeleniya pestitsidov pri ispol'zovanii trekh smesey na etape ochistki. 84 / 5 000 Fig. 1. Pesticide release rates when using three mixtures at the cleaning stage.

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3. Fig. 2. (1-10) Extracted ion chromatograms of wheat samples with 10 μg/kg additives of various pesticides.

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4. Fig. 2. (11-19) Extracted ion chromatograms of wheat samples with 10 μg/kg additives of various pesticides.

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