Nucleophilic Addition of Thiol to Peripheral C=C Bonds of Tetraaryltetracyanoporphyrazine Macrocycle

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Abstract

An irreversible addition reaction of benzylmercaptan to the macrocycle of the cyanoarylporphyrazine family (Ar = p -MeOPh and Nph) was established for the first time. The reaction proceeds along the polarized peripheral semi-isolated double bonds of the macrocycle and takes place under mild conditions. Mass spectrometry and 1H NMR spectroscopy confirm the composition and structure of the products.

About the authors

T. S Lyubova

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

S. A Lermontova

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

L. G Klapshina

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

E. Yu. Ladilina

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: eladilina@gmail.ru

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