Praseodymium and Erbium 1,2,4-Triphenylcyclopentadienyl Complexes

S. S. Degtyareva; Дегтярева С. С.; D. A. Bardonov; Бардонов Д. А.; K. A. Lysenko; Лысенко К. А.; M. E. Minyaev; Миняев М. Е.; I. E. Nifant’ev; Нифантьев И. Э.; D. M. Roitershtein; Ройтерштейн Д. М.

doi:10.31857/S0132344X22600540

Praseodymium and Erbium 1,2,4-Triphenylcyclopentadienyl Complexes

Авторлар: Degtyareva S.S.¹^,2, Bardonov D.A.¹^,2, Lysenko K.A.²^,3, Minyaev M.E.¹^,4, Nifant’ev I.E.¹^,2^,3, Roitershtein D.M.¹^,2^,4
Мекемелер:
1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia
2. National Research University, Higher School of Economics, Moscow, Russia
3. Moscow State University, Moscow, Russia
4. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
Шығарылым: Том 49, № 8 (2023)
Беттер: 504-512
Бөлім: Articles
URL: https://cardiosomatics.ru/0132-344X/article/view/667492
DOI: https://doi.org/10.31857/S0132344X22600540
EDN: https://elibrary.ru/SAGZHE
ID: 667492

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат
Рұқсат жабық

Рұқсат берілді
Рұқсат жабық

Тек жазылушылар үшін

Аннотация
Авторлар туралы
Әдебиет тізімі
Қосымша файлдар
Статистика

Аннотация

The reaction of triphenylcyclopentadienyl potassium with praseodymium and erbium chloride tetrahydrofuranates gives, depending on the reactant ratio, tetranuclear ate complexes, [{(Ph3C5H2)-Pr(THF)}2(µ2-Cl)2(µ3-Cl)3K]2(C7H8)4 (I) and [{(Ph3C5H2)Er(THF)}2(µ2-Cl)2(µ3-Cl)3K(THF)]2 (III), or binuclear ate complexes [(Ph3C5H2)2LnCl(KCl)]2 Ln = Pr (II), Er (IV) (CCDC nos. 2224244 (I), 2224243 (II), 2224245 (III), 2224242 (IV)). The structurally similar complexes I and III are based on the {[Ln2(µ-Cl)3]2(µ-Cl)2K2} core, and in III, the potassium cation is additionally coordinated to the THF molecule. The isostructural complexes II and IV have the binuclear [Ln(µ-Cl)2K]2 core.

Негізгі сөздер

lanthanides, triphenylcyclopentadienyl ligand, X-ray diffraction

Әдебиет тізімі

Arndt S., Okuda J. // Chem. Rev. 2002. V. 102. № 6. P. 1953.
Edelmann F.T. // Comprehensive Organometallic Chemistry III. Elsevier, 2007. P. 1.
Day B.M., Guo F.S., Layfield R.A. //Acc. Chem. Res. 2018. V. 51. № 8. P. 1880.
Evans W.J., Davis B.L. // Chem. Rev. 2002. V. 102. № 6. P. 2119.
Xu J., Gao W., Zhang Y. et al. // J. Organomet. Chem. 2007. V. 692. № 1. P. 1505.
Ye J., Deng D., Gao Y. et al. // Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 2015. V. 134. P. 22.
Zhang X., Ye J., Xu L. et al. // J. Lumin. 2013. V. 139. P. 28.
Yang L., Ye J., Xu L. et al. // RSC Adv. 2012. V. 2. № 30. P. 11529.
Roitershtein D.M., Puntus L.N., Vinogradov A.A. et al. // Inorg. Chem. 2018. V. 57. № 16. P. 10199.
Minyaev M.E., Komarov P.D., Roitershtein D.M. et al. // Organometallics. 2019. V. 38. № 15. P. 2892.
Minyaev M.E., Vinogradov A.A., Roitershtein D.M. et al. // J. Organomet. Chem. 2016. V. 818. P. 128.
Edelmann F.T., Poremba P. // Synthetic Methods of Organometallic and Inorganic Chemistry (Herrman/Brauer) / Eds. Edelmann, F.T., Herrmann, W.A. Stuttgart (Germany): Verlag, 1997. P. 34.
Lochmann L., Trekoval J. // J. Organomet. Chem. 1987. V. 326. № 1. P. 1.
Hirsch S.S., Bailey W. J.J. // Org. Chem. 1978. V. 43. № 21. P. 4090.
APEX-III. Madison (WI, USA): Bruker AXS Inc., 2019.
Krause L., Herbst-Irmer R., Sheldrick G.M., Stalke D. // J. Appl. Crystallogr. 2015. V. 48. P. 3.
Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. P. 3.
Sheldrick G.M. // Acta Crystallogr. C. 2013. V. 71. P. 3.
Бардонов Д.А., Лысенко К.А., Нифантьев И.Э., Ройтерштейн Д.М. // Коорд. химия. 2022. Т. 48. № 5. С. 296 (Bardonov D.A., Lysenko K.A., Nifant’ev I.E., Roitershtein D.M. // Russ. J. Coord. Chem. 2022. V. 48. № 5. P. 295. https://doi.org/10.1134/S1070328422050013
Vinogradov A.A., Komarov P.D., Puntus L.N. et al. // Inorg. Chim. Acta. 2022. V. 533. № 120777.
Komarov P.D., Nifant’ev I.E., Roitershtein D.M., Minyaev M.E. // J. Chem. Crystallogr. 2021. V. 51. P. 352.
Ройтерштейн Д.М., Миняев М.Е., Михайлюк А.А. и др. // Изв. АН. Сер. хим. 2012. Т. 61. С. 1726 (Roitershtein D.M., Minyaev M.E., Mikhaylyuk A.A. et al. // Russ. Chem. Bull. 2012. V. 61. P. 1726).
Fohlmeister L., Jones C. // J. Chem. Crystallogr. 2014. V. 44. P. 301.