Effect of Synthesis and Crystallization Conditions on the Composition and Structure of Europium(III) Mixed-Carboxylate Benzoate–Pentafluorobenzoate Complexes

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

In the present work, the influence of the nature of the solvate molecules and N-donor ligands on the structures of the benzoate–pentafluorobenzoate europium complexes was investigated. It was established that the reaction of europium benzoate (bz) and pentafluorobenzoate (pfb) with 1,10-phenanthroline (phen) in acetonitrile in the presence of toluene, o-xylene, or dichloromethane leads to the formation of compounds [Eu2(phen)2(pfb)4(bz)2]·4C6H5CH3 (I), [Eu2(phen)2(pfb)4(bz)2]·4C6H4(CH3)2 (II), and [Eu2(phen)2(pfb)4 (bz)2]·2.898CH2Cl2 (III), respectively, which possess similar structures. Using quinoline (quin) as the N-donor ligand, mixed-carboxylate coordination polymer crystals [Eu(H₂O)(pfb)2(bz)]n·2n(quin) (IV) were obtained in good yield. The synthesized compounds were characterized by single-crystal X-ray diffraction, IR spectroscopy, and CHN elemental analysis. Non-covalent interactions were analyzed by Hirshfeld surface analysis.

Толық мәтін

Рұқсат жабық

Авторлар туралы

M. Shmelev

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: shmelevma@yandex.ru
Ресей, Moscow

D. Lebedev

Faculty of Chemistry, HSE University

Email: shmelevma@yandex.ru
Ресей, Moscow

A. Chistyakov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: shmelevma@yandex.ru
Ресей, Moscow

J. Voronina

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: shmelevma@yandex.ru
Ресей, Moscow

L. Efromeev

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; Faculty of Chemistry, HSE University

Email: shmelevma@yandex.ru
Ресей, Moscow; Moscow

A. Rogachev

MIREA — Russian technological university

Email: shmelevma@yandex.ru
Ресей, Moscow

A. Sidorov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: shmelevma@yandex.ru
Ресей, Moscow

I. Eremenkoa

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: shmelevma@yandex.ru
Ресей, Moscow

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Әрекет
1. JATS XML
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2. Fig. 1. Structure of complexes I (a), II (b), III (c). Hydrogen atoms are not shown. The dotted lines indicate π···π- and C‒F···π-interactions.

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3. Fig. 2. Fragment of the crystal packing of complexes I (a) and III (b). The dotted lines show π···π- and C‒F···π-interactions.

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4. Fig. 3. Fragment of the crystal packing of compound IV. The dotted lines show π···π-interactions and hydrogen bonds.

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5. Fig. 4. Hirschfeld surface for complexes I (a), II (b), III (c) and IV (d).

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6. Fig. 5. Two-dimensional fingerprint plots corresponding to the C···F (a), H···F (b), O···H (c), C···H (d), C···C (e), and H···H (e) interactions in structure I.

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7. Fig. 6. Two-dimensional fingerprint plots corresponding to the C···F (a), H···F (b), O···H (c), C···H (d), C···C (e), and H···H (e) interactions in structure II.

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8. Fig. 7. Two-dimensional fingerprint plots corresponding to the interactions C F (a), H F (b), O H (c), C H (d), C C (e), H H (f), C Cl (g), and H Cl (h) in structure III.

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9. Fig. 8. Two-dimensional fingerprint plots corresponding to the C···F (a), H···F (b), O···H (c), C···H (d), C···C (e), and H···H (e) interactions in structure IV.

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10. Scheme 1. Synthesis of compounds I‒IV.

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