Synthesis, Supramolecular Self-Organization, and Thermal Behavior of the Double 3D Pseudo-Polymer Complex [Au{S2CN(CH2)6}2]4[Ag5Cl9] Comprising the New Type Silver(I) Anion

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Resumo

New crystalline pseudo-polymer complex [Au{S2CN(CH2)6}2]4[Ag5Cl9] (I) was prepared by inding gold(III) with silver(I) dithiocarbamate from an AuCl3/2.5 M NaCl solution. Complex I is isolated in a preparative yield and structurally characterized. The X-ray diffraction (XRD) data (CIF file CCDC no. 2205197) show that the isomeric cations [Au{S2CN(CH2)6}2]+ (A : 2B : C) and complicated pentanuclear anion [Ag5Cl9]4– are the main structural units of the compound. The supramolecular self-organization of the ionic structural units in complex I occurs due to multiple secondary interactions Cl···S and Ag···S, hydrogen bonds C–H···Cl, and anagostic interactions C–H···Ag leading to the formation of the 3D pseudo-polymer framework. The thermal behavior of complex I is studied by simultaneous thermal analysis to find that the thermolysis of the double Au(III)—Ag(I) compound is accompanied by the quantitative regeneration of the bound metals under comparatively mild conditions.

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Sobre autores

E. Korneeva

Institute of Geology and Nature Management, Far Eastern Branch, Russian Academy of Sciences

Email: alexander.v.ivanov@chemist.com
Rússia, Blagoveshchensk

O. Loseva

Institute of Geology and Nature Management, Far Eastern Branch, Russian Academy of Sciences

Email: alexander.v.ivanov@chemist.com
Rússia, Blagoveshchensk

A. Smolentsev

Nikolaev Institute of Inorganic Chemistry, Siberian Branch

Email: alexander.v.ivanov@chemist.com
Rússia, Novosibirsk

A. Ivanov

Institute of Geology and Nature Management, Far Eastern Branch, Russian Academy of Sciences

Autor responsável pela correspondência
Email: alexander.v.ivanov@chemist.com
Rússia, Blagoveshchensk

Bibliografia

  1. Janz D. M. Dithiocarbamates, in Encyclopedia of Toxicol. (3rd ed), P. Wexler (Ed.), Elsevier. 2014. V. 2. P. 212.
  2. Kaul L., Süss R., Zannettino A., Richter K. // iScience. 2021. V. 24. № 2. Art. 102092.
  3. Sauna Z.E., Shukla S., Ambudkar S. V. // Mol. BioSyst. 2005. V. 1. № 2. P. 127.
  4. Skrott Z., Mistrik M., Andersen K. K. et al. // Nature. 2017. V. 552. P. 194.
  5. Li H., Wang J., Wu C. et al. // Drug Discov. Today. 2020. V. 25. № 6. P. 1099.
  6. McMahon A., Chen W., Li F. // J. Control Release. 2020. V. 319. P. 352.
  7. Hogarth G. // Mini-Rev. Med. Chem. 2012. V. 12. № 12. P. 1202.
  8. Williams M.R.M., Bertrand B., Hughes D. L. et al. // Metallomics. 2018. V. 10. № 12. P. 1655.
  9. Le H.V., Babak M. V., Ehsan M. A. et al. // Dalton Trans. 2020. V. 49. № 22. P. 7355.
  10. Adokoh C.K. // RSC Adv. 2020. V. 10. № 5. P. 2975.
  11. Oladipo D., Mocktar C., Omondi B. // Arabian J. Chem. 2020. V. 13. № 8. P. 6379.
  12. Abás E., Aguirre-Ramírez D., Laguna M., Grasa L. // Biomedicines. 2021. V. 9. № 12. P. 1775.
  13. Oladipo D., Tolufashe G. F., Mocktar C., Omondi B. // Inorg. Chim. Acta. 2021. V. 520. Art. 120316.
  14. Loseva O.V., Lutsenko I. A., Rodina T. A. et al. // Polyhedron. 2022. V. 226. Art. 116097.
  15. Korneeva E.V., Smolentsev A. I., Antzutkin O. N., Ivanov A. V. // Inorg. Chim. Acta. 2021. V. 525. Art. 120383.
  16. Корнеева Е.В., Лосева О. В., Смоленцев А. И., Иванов А. В. // Журн. общ. химии. 2018. Т. 88. № 8. С. 1361 (Korneeva E. V., Loseva O. V., Smolentsev A. I., Ivanov A. V. // Russ. J. Gen. Chem. 2018. V. 88. № 8. P. 1680). https://doi.org/10.1134/S1070363218080200
  17. Корнеева Е.В., Смоленцев А. И., Анцуткин О. Н., Иванов А. В. // Изв. АН. Сер. хим. 2019. № 1. С. 40 (Korneeva E. V., Smolentsev A. I., Antzutkin O. N., Ivanov A. V. // Russ. Chem. Bull. Int. Ed. 2019. V. 68. № 1. P. 40). https://doi.org/10.1007/s11172-019-2413-7
  18. Корнеева Е.В., Новикова Е. В., Лосева О. В. и др. // Коорд. химия. 2021. Т. 47. № 11. С. 707 (Korneeva E. V., Novikova E. V., Loseva O. V. et al. // Russ. J. Coord. Chem. 2021. V. 47. № 11. P. 769). https://doi.org/10.1134/S1070328421090050
  19. Бырько В. М. Дитиокарбаматы. М.: Наука, 1984. 341 с.
  20. Корнеева Е.В., Иванов А. В., Герасименко А.В. и др. // Журн. общ. химии. 2019. Т. 89. № 8. С. 1260 (Korneeva E. V., Ivanov A. V., Gerasimenko A. V. et al. // Russ. J. Gen. Chem. 2019. V. 89. № 8. P. 1642). https://doi.org/10.1134/S1070363219080152
  21. Лосева О.В., Родина Т. А., Иванов А. В. и др. // Коорд. химия. 2018. Т. 44. № 5. С. 303 (Loseva O. V., Rodina T. A., Ivanov A. V. et al. // Russ. J. Coord. Chem. 2018. V. 44. № 10. P. 604). https://doi.org/10.1134/S107032841810007X
  22. APEX2 (version 1.08), SAINT (version 7.03), SADABS (version 2.11). Madison (WI, USA): Bruker AXS Inc., 2004.
  23. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. № 1. P. 3.
  24. Казицына Л.Α., Куплетская Н. Б. Применение УФ-, ИК-, ЯМР- и масс-спектроскопии в органической химии. М.: Изд-во Моск. ун-та., 1979. 240 с.
  25. Гремлих Г. У. Язык спектров. Введение в интерпретацию спектров органических соединений. М.: Брукер Оптик, 2002. 93 с.
  26. Bocian D.F., Pickett H. M., Rounds T. C., Strauss H. L. // J. Am. Chem. Soc. 1975. V. 97. № 4. P. 687.
  27. Boessenkool I.K., Boeyens J. C.A. // J. Cryst. Mol. Struct. 1980. V. 10. № 1–2. P. 11.
  28. Entrena A., Campos J., Gómez J. A. et al. // J. Org. Chem. 1997. V. 62. № 2. P. 337.
  29. Bondi A. // J. Phys. Chem. 1964. V. 68. № 3. P. 441.
  30. Bondi A. // J. Phys. Chem. 1966. V. 70. № 9. P. 3006.
  31. Schmidbaur H., Schier A. // Angew. Chem. Int. Ed. 2015. V. 54. № 3. P. 746.
  32. Helgesson G., Jagner S. // Dalton Trans. 1988. № 8. P. 2117.
  33. Helgesson G., Jagner S. // Dalton Trans. 1990. № 8. P. 2413.
  34. Hassan A., Breeze S. R., Courtenay S. et al. // Orga-nometallics. 1996. V. 15. № 26. P. 5613.
  35. Aboulkacem S., Tyrra W., Pantenburg I. // J. Chem. Cryst. 2006. V. 36. № 2. P. 141.
  36. Yang L., Powel D. R., Houser R. P. // Dalton Trans. 2007. № 9. P. 955.
  37. Alcock N.W. // Adv. Inorg. Chem. Radiochem. 1972. V. 15. № 1. P. 1.
  38. Wang W., Ji B., Zhang Y. // J. Phys. Chem. A. 2009. V. 113. № 28. P. 8132.
  39. Scilabra P., Terraneo G., Resnati G. // Acc. Chem. Res. 2019. V. 52. № 5. P. 1313.
  40. Reddy C.M., Kirchner M. T., Gundakaram R. C. et al. // Chem. Eur. J. 2006. V. 12. № 8. P. 2222.
  41. Awwadi F.F., Willett R. D., Peterson K. A., Twamley B. // Chem. Eur. J. 2006. V. 12. № 35. P. 8952.
  42. Usoltsev A.N., Korobeynikov N. A., Novikov A. S. et al. // Inorg. Chim. Acta. 2020. V. 513. Art. 119932.
  43. Rajput G., Singh V., Gupta A. N. et al. // CrystEngComm. 2013. V. 15. № 23. P. 4676.
  44. Корнеева Е.В., Луценко И. А., Беккер О. Б. и др. // Коорд. химия. 2023. Т. 49. № 2. С. 89 (Korneeva E. V., Lutsenko I. A., Bekker O. B. et al. // Russ. J. Coord. Chem. 2022. V. 48. № 12. P. 924). https://doi.org/10.1134/S1070328422700063
  45. Диаграммы состояния двойных металлических систем: справочник / Под ред. Н. П. Лякишева. М.: Машиностроение, 1996. 992 с.

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2. Fig. 1. Size, particle shape, and energy dispersive spectra of the complexes of [Ag(S2CNHm)] (a) and [Au(S2CNHm)2]4[Ag5Cl9] (b).

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3. Fig. 2. Packing of structural units in crystal I (projection on the xz plane), hydrogen atoms of CH2-groups are omitted for clarity. Alternative positions of Ag(3) and Cl(5) atoms in the composition of [Ag5Cl9]4- anions are not shown.

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4. Fig. 3. Structure of three non-equivalent complex cations of the composition [Au(S2CNHm)2]+ (a-c) and the pentanuclear anion [Ag5Cl9]4- (d); ellipsoids of 50% probability. Uncoloured ellipsoids show alternative positions of Ag(3) and Cl(5) atoms. Symmetric transformations: a2 - x, 1 - y, 1 - z; b1 - x, 2 - y, 1 - z; c2 - x, 1 - y, -z.

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5. Fig. 4. Fragment of the supramolecular ribbon in structure I formed due to secondary Ag---S, Cl---S and Cl---Cl interactions between silver(I) anions and isomeric Au3+ B cations (shown by dashed lines). Symmetric transformations: b1 - x, 1 - y, 1 - z; c2 - x, 1 - y, -z; d1 + x, y, -1 + z.

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6. Fig. 5. Fragment of 2D coordination grid: unification of supramolecular ribbons by isomeric A cations due to pairwise secondary Cl---S interactions (shown by dashed lines). Symmetric transformations: a2 - x, 1 - y, 1 - z; b1 + x, y, -1 + z; c3 - x, 1 - y, -z.

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7. Fig. 6. Spatial orientation of isomeric gold C cations upon binding of neighbouring pseudopolymer layers into a 3D framework. Anagostic C-H∙∙∙∙∙Ag interactions and C-H∙∙∙∙∙Cl hydrogen bonds between silver(I) anions and gold(III) C and B cations (shown as dashed lines). Symmetric transformations: a2 - x, 1 - y, 1 - z; b1 - x, 1 - y, 1 - z; c2 - x, 1 - y, -z; d1 + x, y, -1 + z; ex, y, -1 + z; fx, -1 + y, z.

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8. Fig. 7. TG (a) and DSC (b) curves of complex I. Photograph of the bottom of the crucible after completion of thermolysis (c).

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