Furancarboxylate Coordination Polymers of Gd3+ and Eu3+: Synthesis, Structural Variations, and Biological Properties

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A series of polymer complexes of Gd(III) and Eu(III) with 3-furancarboxylic (HFur) and 5-nitro-
2-furancarboxylic (HNfur) acids differed in the composition and coligands presented by solvent molecules
(CH3OH/C2H5OH/H2O) is synthesized: [Gd(Fur)3(CH3OH)(C2H5OH)]n (I), [Gd(Nfur)3(CH3OH)2]n·
CH3CN (II), [Eu(Fur)3(C2H5OH)]n (III), and [Eu(Nfur)3(H2O)2]n·3CH3CN (IV). According to the X-ray
diffraction (XRD) data, all complexes are 1D coordination polymers in which the lanthanide cation has the
coordination number 8 (LnO8) to form the environment as a doubly augmented triangular prism (I, II) or a
square antiprism (III, IV). The supramolecular levels of the polymers are stabilized due to intra- and intermolecular
hydrogen bonds between the coordinated solvent molecules and O atoms of the chelate-bound
anions of the acid and via two types of noncovalent C–H…O and N–O…π interactions that significantly contribute
to an additional stabilization of the crystal packings. The biological properties of complexes I, II, and
IV are studied with respect to the model nonpathogenic strain Mycolicibacterium smegmatis.

作者简介

M. Uvarova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: yak_marin@mail.ru
Россия, Москва

I. Lutsenko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: yak_marin@mail.ru
Россия, Москва

M. Shmelev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: shmelevma@yandex.ru
Россия, Москва

O. Bekker

Vavilov Institute of General Genetics, Russian Academy of Sciences, Moscow, Russia

Email: yak_marin@mail.ru
Россия, Москва

M. Kiskin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: yak_marin@mail.ru
Россия, Москва

I. Eremenko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

编辑信件的主要联系方式.
Email: yak_marin@mail.ru
Россия, Москва

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版权所有 © М.А. Уварова, И.А. Луценко, М.А. Шмелев, О.Б. Беккер, М.А. Кискин, И.Л. Еременко, 2023