Influence of the choice of kinetic mechanism on predicted structure of lean hydrogen–air flames

Capa

Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Acesso é pago ou somente para assinantes

Resumo

The influence of the choice of a detailed kinetic mechanism (DKM) on the structure of a laminar flame for lean hydrogen-air mixtures has been studied by means of numerical simulation using a CHEMKIN-Pro software module. It is shown that the choice of three detailed kinetic mechanisms (DKMs), differing in the rate constants of elementary reactions, the number of reaction pathways, and the presence of additional components, has virtually no effect on flame propagation velocity and flame structure. It is found that small differences in the local sensitivity of heat release to elementary reactions can provide reliable information on possible ways of influencing flame propagation.

Texto integral

Acesso é fechado

Sobre autores

A. Tereza

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Autor responsável pela correspondência
Email: tereza@chph.ras.ru
Rússia, Moscow

G. Agafonov

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: tereza@chph.ras.ru
Rússia, Moscow

E. Anderzhanov

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: tereza@chph.ras.ru
Rússia, Moscow

A. Betev

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: tereza@chph.ras.ru
Rússia, Moscow

S. Khomik

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: tereza@chph.ras.ru
Rússia, Moscow

T. Cherepanova

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: tereza@chph.ras.ru
Rússia, Moscow

A. Cherepanov

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: tereza@chph.ras.ru
Rússia, Moscow

S. Medvedev

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: tereza@chph.ras.ru
Rússia, Moscow

Bibliografia

  1. A.M. Domashenko, A.V. Stepanov. Vesti gazovoj nauki 51(2), 211 (2022).
  2. S.V. Korobtsev, V.N. Fateev, R.O. Samsonov, S.I. Kozlov. Transport na alternativnom toplive 5, 68 (2008).
  3. A.A. Abagyan, E.O. Adamov, E.V. Burlakov. Proc. IAEA Conf. (Intern.). Vienna, Austria. 1996. IAEA-J4-TC972. P. 46.
  4. G. Saji, Nucl. Eng. Des. 307, 64 (2016). http://dx.doi.org/10.1016/j.nucengdes.2016.01.039
  5. Bentaib, N. Meynet, A. Bleyer. Nucl. Eng. 47(1), 26 (2015). https://doi.org/10.1016/j.net.2014.12.001
  6. Kirillov, N. Kharitonova, R. Sharafutdinov, N. Krenniikov. Nucl. Rad. Safety J. 2(84), 26 (2017).
  7. Yakovenko, A. Kiverin, K. Melnikova. Fluids 6(1), 21 (2021). https://doi.org/10.3390/fluids6010021
  8. I.S. Yakovenko, I.S. Medvedkov, A.D. Kiverin. Russ. J. Phys. Chem. B. 16, 294 (2022). https://doi.org/10.1134/S1990793122020142
  9. A.M. Tereza, G.L. Agafonov, E.K. Anderzhanov, A.S. Betev, S.P. Medvedev, S.V. Khomik, T.T. Cherepanova. Russ. J. Phys. Chem. B. 17(4), 974 (2023). https://doi.org/10.1134/S1990793123040309
  10. P. Krivosheyev, Y. Kisel, A. Skilandz, K. Sevrouk, O. Penyazkov, A. Tereza. Int. J. Hydrogen Energy 66, 81 (2024). https://doi.org/10.1016/j.ijhydene.2024.03.363
  11. D.A. Frank-Kamenetskii. Diffusion and Heat Transfer in Chemical Kinetics. (Plenum, New York, 1969).
  12. A.A. Azatyan, S.K. Abramov, A.A. Borisov, V.M. Prokopenko. Russ. J. Phys. Chem. A. 86 (3), 355 (2012). https://doi.org/10.1134/S0036024412030053
  13. A.L. Sanchez, F.A. Williams. Prog. Energy Combust. Sci. 41, 1 (2014). https://doi.org/10.1016/j.pecs.2013.10.002
  14. A.M. Tereza, G.L. Agafonov, E.K. Anderzhanov et al. Russ. J. Phys. Chem. B. 17 (6), 1294. https://doi.org/10.1134/S1990793123060246
  15. D.A. Knyazkov, A.G. Shmakov, O.P. Korobeinichev. Combust. Flame 151, 37 (2007). https://doi.org/10.1016/j.combustflame.2007.06.011
  16. D.A. Knyazkov, V. Shvartsberg, A. Dmitriev et al. Combustion Explosion and Shock Waves 53, 491 (2017). https://doi.org/10.1134/S001050821705001X
  17. A.G. Shmakov. Doctoral Dissertation in Chemistry. (Voevodsky Inst. of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, 2022).
  18. A.E. Elyanov, A.I. Gavrikov, V.V. Golub, A.Y. Mikushkin, V.V. Volodin. Process Saf. Environm. Prot. 164, 50 (2022). https://doi.org/10.1016/j.psep.2022.06.007
  19. D.L. Baulch, C.T. Bowman, C.J. Cobos et al. J. Phys. Chem. Ref. Data. 34(3), 757 (2005). https://doi.org/10.1063/1.1748524
  20. A.M. Tereza, G.L. Agafonov, E.K. Anderzhanov et al. Russ. J. Phys. Chem. B 16, 686 (2022). https://doi.org/10.1134/S1990793122040297
  21. Keromnes, W.K. Metcalfe, K.A. Heufer et al. Combust. and Flame 160, 995 (2013). https://doi.10.1016/j.combustflame.2013.01.001
  22. A.A. Konnov. Combust. and Flame 203, 14 (2019). https://doi.org/10.1016/j.combustflame.2019.01.032
  23. CHEMKIN-Pro 15112, Reaction Design, San Diego, CK-TUT-10112-1112-UG-1., 2011.
  24. S.P. Karkach, V.I. Osherov. J. Chem. Phys. 110, 11918 (1999). http://dx.doi.org/10.1063/1.479131
  25. J.V. Michael, J.W. Sutherland, L.B. Harding et al. // Proc. Combust. Symp. 28, 1471 (2000).
  26. P.A. Vlasov, V.N. Smirnov, A.M. Tereza. Russ. J. Phys. Chem. B 10, 456 (2016). https://doi.10.1134/S1990793116030283
  27. S. Medvedev, G. Agafonov, S. Khomik. Acta Astronaut. 126, 150 (2016). https://doi.org/10.1016/j.actaastro.2016.04.019
  28. A.E. Lutz, R.J. Kee, J.A. Miller. Sandia National Laboratories, Livermore, CA, SAND 87-82481998.
  29. R.J. Kee, J.F. Grcar, M.D. Smooke, J.A. Miller. Sandia National Laboratories, Livermore, CA, SAND85-8240, 1985.
  30. V.V. Roenko, A.P. Karmes. Tekhnologia pozharotushenia 3, 15 (2017).
  31. B.E. Gel’fand, O.M. Popov, B.B. Chaivanov. Hydrogen: Parameters of Combustion and Explosion (Fizmatlit, Moscow, 2008) [In Russian].

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML
Baixar
2. Fig. 1. Concentration and temperature profiles (a) and temperature sensitivity analysis to reactions determining heat release in a laminar flame (b), calculated using the DCM from [10] for a mixture of 15% H2 in air under normal initial conditions

Baixar (405KB)
Metadados
3. Fig. 2. The same as in Fig. 1, but using the DCM from [21].

Baixar (416KB)
Metadados
4. Fig. 3. The same as in Fig. 1, but using the DCM from [22].

Baixar (416KB)
Metadados

Declaração de direitos autorais © Russian Academy of Sciences, 2025