Kinetics the proliferation of correlations in multiple quantum NMR spectroscopy

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Resumo

It is shown that the number of spins in clusters of coherently correlated states arising under conditions of multiplequantum NMR – spectroscopy in a solid increases exponentially with time. The Smolukhovsky equation was used to study the above processes. Possible processes of cluster degradation were not taken into account. The results obtained are in good agreement with the experimental data, at least up to about 105 spins in the cluster.

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Sobre autores

V. Bodneva

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: ya-andylun2012@yandex.ru
Rússia, Moscow

A. Vetchinkin

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: ya-andylun2012@yandex.ru
Rússia, Moscow

B. Lidskiy

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: ya-andylun2012@yandex.ru
Rússia, Moscow

A. Lundin

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Autor responsável pela correspondência
Email: ya-andylun2012@yandex.ru
Rússia, Moscow

S. Umanskii

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: ya-andylun2012@yandex.ru
Rússia, Moscow

Y. Chaikina

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: ya-andylun2012@yandex.ru
Rússia, Moscow

A. Shushin

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: ya-andylun2012@yandex.ru
Rússia, Moscow

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