Cyanomethyl-Substituted Furazanoazepines: Synthesis, Structure, Enthalpy of Formation, and Ballistic Efficiency

D. B. Lempert; Лемперт Д. Б.; E. L. Ignatieva; Игнатьева Е. Л.; A. I. Stepanov; Степанов А. И.; D. V. Dashko; Дашко Д. В.; A. I. Kazakov; Казаков А. И.; A. V. Nabatova; Набатова А. В.; G. V. Shilov; Шилов Г. В.; A. N. Utenyshev; Утенышев А. Н.; S. M. Aldoshin; Алдошин С. М.

doi:10.31857/S0207401X23050060

Cyanomethyl-Substituted Furazanoazepines: Synthesis, Structure, Enthalpy of Formation, and Ballistic Efficiency

作者: Lempert D.B.¹, Ignatieva E.L.¹, Stepanov A.I.², Dashko D.V.², Kazakov A.I.¹, Nabatova A.V.¹, Shilov G.V.¹, Utenyshev A.N.¹, Aldoshin S.M.¹
隶属关系:
1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
2. Special Design and Technological Bureau “Technolog”
期: 卷 42, 编号 5 (2023)
页面: 11-19
栏目: Combustion, explosion and shock waves
URL: https://cardiosomatics.ru/0207-401X/article/view/674864
DOI: https://doi.org/10.31857/S0207401X23050060
EDN: https://elibrary.ru/GDFSCE
ID: 674864

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详细

7-Cyanomethyl-7Н-difurazano[3,4-b:3′,4′-f]furoxano[3″,4″-d]azepine (Az(O)CH2CN) and 7-cyanomethyl-7Н-trifurazano[3,4-b:3′,4′-d:3″,4″-f]azepine (AzCH2CN) are synthesized for the first time as potential dispersants of solid fuels for gas generator engines; their molecular structure, enthalpies of combustion, and formation are determined; and the relative aircraft flight range is estimated when using Az(O)CH2CN and AzCH2CN as fuel dispersants.

关键词

N-cyanomethyl derivatives of 7H-trifurazanoazepines and 7H-difurazanofuroxanoazepines, synthesis, structure, enthalpy of formation, ballistic efficiency

作者简介

D. Lempert

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: lempert@icp.ac.ru
142432, Chernogolovka, Russia

E. Ignatieva

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: lempert@icp.ac.ru
142432, Chernogolovka, Russia

A. Stepanov

Special Design and Technological Bureau “Technolog”

Email: lempert@icp.ac.ru
192076, St. Petersburg, Russia

D. Dashko

Special Design and Technological Bureau “Technolog”

Email: lempert@icp.ac.ru
192076, St. Petersburg, Russia

A. Kazakov

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: lempert@icp.ac.ru
142432, Chernogolovka, Russia

A. Nabatova

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: lempert@icp.ac.ru
142432, Chernogolovka, Russia

G. Shilov

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: lempert@icp.ac.ru
142432, Chernogolovka, Russia

A. Utenyshev

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: lempert@icp.ac.ru
142432, Chernogolovka, Russia

S. Aldoshin

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: lempert@icp.ac.ru
142432, Chernogolovka, Russia

参考

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