Nickel Based Ni–Ce 1– x  Zr  x  O 2  Catalysts Prepared by Pechini Method for CO 2  Methanation

V. P. Pakharukova; Пахарукова В. П.; O. A. Stonkus; Стонкус О. А.; N. A. Kharchenko; Харченко Н. А.; V. N. Rogozhnikov; Рогожников В. Н.; Yu. A. Chesalov; Чесалов Ю. А.; A. M. Gorlova; Горлова А. М.; A. A. Saraev; Сараев А. А.; D. I. Potemkin; Потемкин Д. И.

doi:10.31857/S0453881123050064

Nickel Based Ni–Ce_1–xZr_xO₂ Catalysts Prepared by Pechini Method for CO₂ Methanation

Autores: Pakharukova V.P.¹^,2, Stonkus O.A.¹, Kharchenko N.A.¹^,2, Rogozhnikov V.N.¹, Chesalov Y.A.¹, Gorlova A.M.¹^,2, Saraev A.A.¹, Potemkin D.I.¹^,2
Afiliações:
1. Boreskov Institute of Catalysis SB RAS
2. Novosibirsk State University
Edição: Volume 64, Nº 5 (2023)
Páginas: 648-660
Seção: ARTICLES
URL: https://cardiosomatics.ru/0453-8811/article/view/660340
DOI: https://doi.org/10.31857/S0453881123050064
EDN: https://elibrary.ru/NBGITO
ID: 660340

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Resumo

Nickel-based Ni–Ce_{1 –} _xZr_xO₂ catalysts were prepared by Pechini method and their catalytic performance towards CO₂ methanation reaction was studied. It was shown that the catalysts exhibit high catalytic activity comparable to the activity of industrial methanation catalyst NIAP-07-05. The catalysts were characterized using a complex of X-ray diffraction methods with experiments on synchrotron radiation, high-resolution electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy. It is shown that the preparation method makes it possible to achieve a high dispersion of nickel-containing particles formed during the decomposition of the Ni–Ce–Zr–O substitutional solid solution obtained during the synthesis. However, due to the decorating effect, the surface of nickel-containing particles is poorly accessible to reagents. For this reason, the Ni–Ce_{1 –} _xZr_xO₂ catalysts obtained by the Pechini method are less active than the supported Ni/Ce_{1 –} _xZr_xO₂ catalysts.

Palavras-chave

CO₂ methanation, nickel-based catalyst, cerium-zirconium oxide, atomic pair distribution analysis, electron microscopy, synchrotron radiation

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