Electron excitation transfer in nanoclusters of colloidal quantum dots InP/ZnS doped with manganese ions
- Authors: Popkov D.S.1, Pevtsov D.N.2,1, Nickolenko L.M.2,1, Razumov V.F.2,1
- 
							Affiliations: 
							- Moscow Institute of Physics and Technology
- Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS
 
- Issue: Vol 58, No 6 (2024)
- Pages: 456-463
- Section: PHOTONICS
- URL: https://cardiosomatics.ru/0023-1193/article/view/681212
- DOI: https://doi.org/10.31857/S0023119324060058
- EDN: https://elibrary.ru/TIAMMH
- ID: 681212
Cite item
Abstract
Colloidal indium phosphide quantum dots with a thin shell of zinc sulfide doped with manganese have been synthesized. Nanoclusters were fabricated based on the obtained nanocrystals. The effect of doping of nanocrystals on the process of Förster resonance transfer of electronic excitation and the spectral and luminescent properties of nanoclusters was studied for the first time. It has been shown that the luminescence of such clusters is radically different from the luminescence of undoped clusters and depends on the size of the nanocrystals. It is shown that the composition of particles participating in Förster transport depends on the moment of observation.
Full Text
 
												
	                        About the authors
D. S. Popkov
Moscow Institute of Physics and Technology
														Email: pevtsov.dn@mipt.ru
				                					                																			                												                	Russian Federation, 							Dolgoprudny						
D. N. Pevtsov
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS; Moscow Institute of Physics and Technology
							Author for correspondence.
							Email: pevtsov.dn@mipt.ru
				                					                																			                												                	Russian Federation, 							Chernogolovka; Dolgoprudny						
L. M. Nickolenko
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS; Moscow Institute of Physics and Technology
														Email: pevtsov.dn@mipt.ru
				                					                																			                												                	Russian Federation, 							Chernogolovka; Dolgoprudny						
V. F. Razumov
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS; Moscow Institute of Physics and Technology
														Email: pevtsov.dn@mipt.ru
				                					                																			                												                	Russian Federation, 							Chernogolovka; Dolgoprudny						
References
- Razumov V. F. Role of collective interaction effects in nanoclusters of colloidal quantum dots. High Energy Chemistry, 2014, 48(b), 419.
- Masters B. R. Paths to Förster’s resonance energy transfer (FRET) theory. The European Physical Journal H, 2014, 39, 87-139.
- Nikolenko L. M., Pevtsov D. N., Gak V. Y., Nazarov V. B., Akimov A. V., Tovstun S. A., Razumov V. F. (2024). Delayed fluorescence of InP: Mn/ZnS nanocrystals. Journal of Photochemistry and Photobiology A: Chemistry, 448, 115298.
- R. Beaulac, P.I. Archer, S.T. Ochsenbein, D.R. Gamelin. Mn2+-doped CdSe quantum dots: New inorganic materials for spin-electronics and spin-photonics, Adv. Funct. Mater. 18 (2008) 3873–3891.
- R. Beaulac, P.I. Archer, D.R. Gamelin. Luminescence in colloidal Mn2+-doped semiconductor nanocrystals, J. Solid State Chem. 181 (2008) 1582–1589.
- M. Tanaka, J. Qi, Y. Masumoto. Comparison of energy levels of Mn2+ in nanosized- and bulk-ZnS crystals, J. Lumin. 87–89 (2000) 472–474.
- Shiliang Meia, Xian Weia, Dan Yanga, Danlu Sua, Wu Yanga, Guilin Zhanga, Zhe Hua, BoBo Yangb, Hanqing Daib, Fengxian Xiea, Wanlu Zhanga, Ruiqian Guo. Journal of Luminescence, 212 (2019), 264–270
- Brichkin, S. B., Tovstun, S. A., Spirin, M. G., Razumov, V. F. (2017). Förster resonance energy transfer in nanoclusters of InP@ ZnS colloidal quantum dots with dodecylamine ligand shells. High Energy Chemistry, 51, 455-461.
- Tovstun, S. A., Gadomska, A. V., Spirin, M. G., Razumov V. F. (2022). Extracting the homogeneous and inhomogeneous linewidths of colloidal quantum dots from the excitation-emission matrix. Journal of Luminescence, 252, 119420.
- Yuldasheva D. K., Pevtsov D. N., Gadomska A. V., Tovstun S. A. (2022). Kinetics of Nonradiative Energy Transfer between Close-Packed InP/ZnS Nanocrystals. High Energy Chemistry, 56(6), 399–410.
Supplementary files
 
				
			 
					 
						 
						 
						 
						 
									

 
  
  
  Email this article
			Email this article 
 Open Access
		                                Open Access Access granted
						Access granted






