Photochemical oxidation of antibacterial drugs in the presence of oxygen-containing additives

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Abstract

The article deals with the photochemical oxidation of nitrofural and tetracycline in the presence of oxygen-containing additives (hydrogen peroxide, peroxydisulfuric acid, potassium persulfate). It was found that the addition of oxygen-containing additives significantly increases the efficiency and rate of APS degradation. The highest degradation efficiency is achieved using hydrogen peroxide, but the high cost of the reagent allows us to consider peroxydisulfuric acid and potassium persulfate as potential alternatives.

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About the authors

T. G. Lyubushkin

Mendeleev University of Chemical Technology

Author for correspondence.
Email: timlub2000@gmail.com
Russian Federation, 1st Miusskaya St., 9, bldg. 1, 125047 Moscow

N. A. Ivancova

Mendeleev University of Chemical Technology

Email: timlub2000@gmail.com
Russian Federation, 1st Miusskaya St., 9, bldg. 1, 125047 Moscow

E. N. Kuzin

Mendeleev University of Chemical Technology

Email: timlub2000@gmail.com
Russian Federation, 1st Miusskaya St., 9, bldg. 1, 125047 Moscow

V. I. Tikhonova

Mendeleev University of Chemical Technology

Email: timlub2000@gmail.com
Russian Federation, 1st Miusskaya St., 9, bldg. 1, 125047 Moscow

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2. Fig. 1. The degree of photodestruction of individual APS solutions: 1 – nitrofural, IKL lamp, 2 – tetracycline, IKL lamp, 3 – nitrofural, RLND lamp, 4 – tetracycline, RLND lamp.

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3. Fig. 2. Photodestruction of AFS in the presence of H2S2O8: 1 – nitrofural, IKL lamp, 2 – tetracycline, IKL lamp, 3 – nitrofural, RLND lamp, 4 – tetracycline, RLND lamp.

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4. Fig. 3. Photodestruction of APS in the presence of K2S2O8: 1 – nitrofural, IKL lamp, 2 – tetracycline, IKL lamp, 3 – nitrofural, RLND lamp, 4 – tetracycline, RLND lamp.

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5. Fig. 4. Photodestruction of APS in the presence of H2O2: 1 – nitrofural, IKL lamp, 2 – tetracycline, IKL lamp, 3 – nitrofural, RLND lamp, 4 – tetracycline, RLND lamp.

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