Extraction of actinides and lanthanides from nitric acid solutions with phosphorylated pyrazines

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Abstract

The extraction of U(VI), Th(IV), Am(III), and lanthanides(III) from nitric acid solutions with solutions of phosphorylated pyrazines in organic solvents has been studied. The stoichiometry of the extracted complexes was determined, and the in uence of the structure of the extractant and the concentration of HNO3 in the aqueous phase on the e ciency of the extraction of metal ions into the organic phase was considered. It has been established thatm among the studied compounds, bis(diphenylphosphine)quinoxaline dioxide has the highest extraction ability with respect to actinides and lanthanides in nitric acid media.

About the authors

A. N. Turanov

Osip’yan Institute of Solid State Physics, Russian Academy of Sciences

V. K. Karandashev

Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences

O. I. Artyushin

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

E. V. Smirnova

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

G. V. Kostikova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

A. M. Fedoseev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

V. K. Brel

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: v_brel@mail.ru

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