Sinthesis and Properties of Hard Carbon Materials Made of Molybdenum-Doped Viscose Fiber for Negative Electrodes of Sodium-Ion Batteries

V. V. Zheleznov; Железнов В. В.; N. S. Saenko; Саенко Н. С.; V. Yu. Maiorov; Майоров В. Ю.; A. Yu. Ustinov; Устинов А. Ю.; T. A. Sokol’nitskaya; Сокольницкая Т. А.; V. G. Kuryavyi; Курявый В. Г.; D. Kh. Shlik; Шлык Д. Х.; A. A. Sokolov; Соколов А. А.; D. P. Opra; Опра Д. П.

doi:10.31857/S0044457X22600931

Sinthesis and Properties of Hard Carbon Materials Made of Molybdenum-Doped Viscose Fiber for Negative Electrodes of Sodium-Ion Batteries

Authors: Zheleznov V.V.¹, Saenko N.S.¹, Maiorov V.Y.¹, Ustinov A.Y.¹, Sokol’nitskaya T.A.¹, Kuryavyi V.G.¹, Shlik D.K.¹, Sokolov A.A.¹, Opra D.P.¹
Affiliations:
1. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences
Issue: Vol 68, No 3 (2023)
Pages: 373-382
Section: НЕОРГАНИЧЕСКИЕ МАТЕРИАЛЫ И НАНОМАТЕРИАЛЫ
URL: https://cardiosomatics.ru/0044-457X/article/view/665291
DOI: https://doi.org/10.31857/S0044457X22600931
EDN: https://elibrary.ru/JBIXIM
ID: 665291

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Abstract
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Abstract

Herein, a method for the preparation of hard carbon via carbonization of chemically modified (molybdenum-doped) commercially available viscose fiber was developed. The effects of a molybdenum dopant on carbonization conditions were studied. The carbonization products retained the fibrous structure and flexibility. The structural features of the synthesized hard carbon materials were investigated, and their relationships to the carbonization temperature and the amount of the molybdenum dopant were analyzed. The texture of materials was studied, and correlations between the specific surface area and porosity, on the one hand, and the synthesis conditions, on the other, were discovered. The usefulness of the products as anode materials for sodium-ion batteries was evaluated. The electrochemical tests, together the extant relevant data, indicate that molybdenum induces the structural rearrangement of the carbon framework upon annealing, accompanied by the growth and ordering of graphite-like nanoclusters. The material prepared at 1050°C exhibited the best electrochemical performances among the synthesized products and the stable cyclability with a capacity of 290 (mA h)/g at a current density of 25 mA/g.

Keywords

hard carbon, viscose, heteroatomic doping, molybdenum, anode material

References

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