Effect of Fluorine on Thermoluminescence in LiMgPO4

M. O. Kalinkin; Калинкин М. О.; D. A. Akulov; Акулов Д. А.; O. I. Gyrdasova; Гырдасова О. И.; R. M. Abashev; Абашев Р. М.; A. I. Surdo; Сюрдо А. И.; N. I. Medvedeva; Медведева Н. И.; D. G. Kellerman; Келлерман Д. Г.

doi:10.31857/S0044457X22601328

Effect of Fluorine on Thermoluminescence in LiMgPO4

作者: Kalinkin M.O.¹, Akulov D.A.¹, Gyrdasova O.I.¹, Abashev R.M.¹^,2, Surdo A.I.¹, Medvedeva N.I.¹, Kellerman D.G.¹
隶属关系:
1. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences
2. Ural Federal University named after the first President of Russia B.N. Yeltsin
期: 卷 68, 编号 2 (2023)
页面: 265-270
栏目: НЕОРГАНИЧЕСКИЕ МАТЕРИАЛЫ И НАНОМАТЕРИАЛЫ
URL: https://cardiosomatics.ru/0044-457X/article/view/665312
DOI: https://doi.org/10.31857/S0044457X22601328
EDN: https://elibrary.ru/LOUCIV
ID: 665312

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详细

Fluorine-doped lithium magnesium phosphate has been studied for the first time. It has been shown that fluorine significantly enhances the intensity of thermally stimulated luminescence. To find the preferred positions of fluorine and structural distortions caused by aliovalent substitution, ab initio calculations have been performed, which demonstrate that fluorine is not included into the (PO4)3– anion; rather, it promotes the formation of clusters simultaneously containing lithium and fluorine ions.

关键词

phosphate, lithium fluoride, thermoluminescence, dosimetry, defects

参考

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