Potentiometraic Method for Determining Biologically Non-Degradable Antimicrobial Substances

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Resumo

Ion selective electrodes (ISEs) based on polymer plasticized membranes have been developed for the determination of benzalkonium chloride (alkyldimethylbenzylammonium), the active component being cesium bis-octodecyl-2-sulfonio-closo-decaborate Cs[B10H9S(C18H37)2] (sensor A). For the determination of norfloxacin hydrochloride, the active component is potassium tris-octodecyl-1-ammonio-closo-decaborate K[B10H9N(C18H37)3] (sensor B). It has been shown that the electrodes have a reversible potentiometric response with respect to the analyzed cations in the presence of a number of other inorganic and organic cations. The influence of the concentration of the electrode-active substance on the electrochemical characteristics of the manufactured sensor has been studied. The optimal composition of the ion-sensitive membrane has been found. It has been determined that the developed sensors provide a wide range of detectable concentrations (for sensor A, 2 × 10–7–1 × 10–2; for sensor B, 1 × 10–7–1 × 10–2) and a low detection limit (for sensor A, 1 × 10–7 M; for sensor B, 8 × 10–8 M). New ISEs can be recommended for direct potentiometric detection of free ions in water bodies and water extracts of soils.

Sobre autores

E. Turyshev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: tyrishev@gmail.com
119991, Moscow, Russia

A. Kubasov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: tyrishev@gmail.com
119991, Moscow, Russia

A. Golubev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: tyrishev@gmail.com
119991, Moscow, Russia

K. Zhizhin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: tyrishev@gmail.com
119991, Moscow, Russia

N. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Autor responsável pela correspondência
Email: tyrishev@gmail.com
119991, Moscow, Russia

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Declaração de direitos autorais © Е.С. Турышев, А.С. Кубасов, А.В. Голубев, К.Ю. Жижин, Н.Т. Кузнецов, 2023