Characterization of New Pentanuclear Copper(II) and REE(III) Carboxylate Complexes

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Resumo

New pentanuclear complexes [Cu3M2(CHF2COO)12(H2O)8]·2H2O, where M = Er (I) and Nd (II), were synthesized by reacting individual copper haloacetates and REE in aqueous solution. The molecular structure of complex I was determined by single crystal X-ray diffraction analysis (CIF file CCDC no. 2159724). The structural features of the complexes and the nature of the carboxylate bridges between the metal centers affect the properties of these complexes; therefore, two similar compounds with the monochloroacetate ligand were prepared for comparison: [Cu3M2(СH2ClCOO)12(H2O)8]·2H2O, where M = Er (III) and Nd (IV). Compounds III and IV are isostructural to previously studied complexes of this type with other REE. Compounds I–IV were characterized by X-ray diffraction analysis and IR spectroscopy, and their thermal behavior was studied. To confirm the formation of precursors of molecular species of crystalline compound I, the solute species of the complexes were determined by electrospray ionization mass spectrometry (ESI-MS).

Sobre autores

O. Pushikhina

Moscow State University

Email: pushikhina_chem@mail.ru
119991, Moscow, Russia

E. Karpova

Moscow State University

Email: karpova@inorg.chem.msu.ru
119991, Moscow, Russia

D. Tsarev

Mitoengineering Research Institute, Moscow State University

Email: karpova@inorg.chem.msu.ru
119991, Moscow, Russia

V. Tafeenko

Moscow State University

Email: karpova@inorg.chem.msu.ru
119991, Moscow, Russia

T. Shatalova

Moscow State University

Autor responsável pela correspondência
Email: karpova@inorg.chem.msu.ru
119991, Moscow, Russia

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Declaração de direitos autorais © О.С. Пушихина, Е.В. Карпова, Д.А. Царёв, В.А. Тафеенко, Т.Б. Шаталова, 2023