SYNTHESIS AND SPECTRAL PROPERTIES OF HALOGEN SUBSTITUTED Cu(II)-TETRAPHENYLPORPHYRINS

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Abstract

The exhaustive halogenation of the β-positions of Cu(II)-5,10,15,20-tetra-(2,6-difluorophenyl)porphyrin using N-bromosuccinimide and N-chlorosuccinimide in dimethylformamide was carried out. Cu(II)-β-octachloro-(2,3,4,5,6-pentafluorophenyl)porphyrin was synthesised by the interaction of Cu(II)-5,10,15,20-tetra-(2,3,4,5,6-pentafluorophenyl)porphyrin with N-chlorosuccinimide in dimethylformamide. Using the complexation reaction of β-octabromo-5,10,15,20-tetra-(2,6-difluorophenylporphyrin, β-octachloro-5,10,15,20-tetra-(2,6-difluoro-phenylporphyrin and β-octachloro-5,10,15,20-tetra-(2,3,4,5,6-pentafluorophenyl)porphyrin with copper salts in dimethylformamide under mild conditions, the corresponding copper(II) complexes were obtained. The coordination reaction kinetics of β-octabromo-5,10,15,20-tetra-(2,6-difluorophenyl-porphyrin with copper chloride in dimethylformamide has been studied. The kinetic parameters of the reaction have been calculated. The obtained compounds were identified by UV-Vis, 1H NMR spectroscopy, mass spectrometry, elemental analysis methods. X-ray diffractograms were obtained for a number of copper complexes.

About the authors

S. V. Zvezdina

Krestov Institute of Solutions Chemistry of the Russian Academy of Sciences

Email: email@example.com
Ivanovo, Russia

N. V. Chizhova

Krestov Institute of Solutions Chemistry of the Russian Academy of Sciences

Ivanovo, Russia

N. Zh. Mamardashvili

Krestov Institute of Solutions Chemistry of the Russian Academy of Sciences

Email: zvezdina75@mail.ru
Ivanovo, Russia

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