Ion-Selective Membrane Electrode for Determination of the Octahydrotriborate Anion

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

An ion-selective electrode (ISE) based on a plasticized polyvinyl chloride membrane chemically doped with tetradecylammonium octahydrotriborate ([(С10H21)4N+]
) has been developed. It is shown that the electrode has a reversible potentiometric response with respect to the octahydrotriborate anion in the presence of a number of other inorganic anions. The influence of the concentration of the electrode-active material and the nature of the plasticizer in the membrane phase on the electrochemical characteristics of the fabricated sensor have been studied. The optimal composition of the ion-sensitive membrane has been found. It has been found that the developed sensor provides a wide range of detectable concentrations of 
 (1 × 10–7…1 × 10–2) and a low detection limit (10–7.3 M). The new ISE can be recommended for direct potentiometric detection of free octahydrotriborate anions in technological aqueous solutions.

Авторлар туралы

A. Kopytin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: tyrishev@gmail.com
119991, Moscow, Russia

E. Turyshev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: tyrishev@gmail.com
119991, Moscow, Russia

M. Madraimov

Mendeleev University of Chemical Technology of Russia

Email: tyrishev@gmail.com
125047, Moscow, Russia

A. Kubasov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: tyrishev@gmail.com
119991, Moscow, Russia

K. Zhizhin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: tyrishev@gmail.com
119991, Moscow, Russia

L. Shpigun

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: tyrishev@gmail.com
119991, Moscow, Russia

N. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: tyrishev@gmail.com
119991, Moscow, Russia

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Қосымша файлдар


© А.В. Копытин, Е.С. Турышев, М.Ш. Мадраимов, А.С. Кубасов, К.Ю. Жижин, Л.К. Шпигун, Н.Т. Кузнецов, 2023