Spectrophotometric study of basic properties of glycosylated tetraphenylporphin derivatives

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Abstract

The paper presents the results of spectrophotometric study of the basic properties of glycosylated substituted derivatives of 5,10,15,20-tetraphenylporphyrin, namely 5-(4′- O -galactosylphenyl)-10,15,20-tris( N -methylpyridin-3-yl)porphine, 5,15-bis(4′- O -galactosylphenyl)-10,20-bis( N -methylpyridin-3-yl)porphine, 5,10,15,20-tetra( N -methylpyridin-3-yl)porphin, 5,10,15,20-tetra(4- O -galactosylphenyl)porphin. The basic properties of the studied ligands in acetonitrile at 298 K were studied by spectrophotometric method. The effect of glycosylated fragments, as constituents of a macromolecule, on protolytic equilibria during acid-base interactions of the ligand in basic media and the change in the reactivity of porphyrin ligands depending on the nature of the peripheral substituent was analyzed.

About the authors

Yu. B. Ivanova

G.A. Krestov Institute of Chemistry of Solutions, Russian Academy of Sciences

Email: jjiv@yandex.ru

S. G Pukhovskaya

Ivanovo State University of Chemical Technology

A. V Lyubimtsev

Ivanovo State University of Chemical Technology

S. A Syrbu

G.A. Krestov Institute of Chemistry of Solutions, Russian Academy of Sciences;Ivanovo State University of Chemical Technology

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