Complex of Mn(II) Perchlorate with (2-Methylenepropane-1,3-diyl)bis(diphenylphosphine Oxide): Synthesis, Structure, and Double Luminescence

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Abstract

The reaction of Mn(ClO4)2·6H2O with (2-methylenepropan-1,3-diyl)bis(diphenylphosphine oxide) (L) in a methanol medium yielded a previously unknown complex [MnL2(MeOH)2](ClO4)2. According to X-ray diffraction data, its Mn2+ ion has a distorted octahedral environment formed by two chelate L ligands and two coordinated methanol molecules. At 298 K, this complex exhibits low-intensity dual luminescence, the low-energy component of which is attributed to Mn2+-centered phosphorescence, and the high-energy component is assigned to intraligand fluorescence.

About the authors

M. P Davydova

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

I. Yu. Bagryanskaya

N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the Russian Academy of Sciences

M. I Rakhmanova

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

V. K Brel

A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Email: v_brel@mail.ru

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