Rhodamine 6G based molecular ion-active switches of optical and fluorescent properties

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A series of rhodamine 6G derivatives with o -hydroxyarylime substituents was synthesized. The obtained compounds in acetonitrile are capable of H+ induced transformation of the spirolactam form into open form. The process is accompanied by the formation of new long-wave absorption maxima at 527-529 nm and fluorescence bands at 557-560 nm. The compound containing 2-hydroxy-4-dimethylaminophenyl substituent in the presence of Zn2+ cations displays switching of emission at 429 nm. This fluorescence is quenched selectively by the CN- anion. Copper(II) cations cause the transformation of the spirostructure of rhodamine with a 2-hydroxy-3- tert -butylbenzofuran group into an open form. Isomerization occurs with a chromogenic naked-eye effect - a change in the color of the solution from pale yellow to pink and the appearance of fluorescence at 556 nm. The observed ion-induced spectral transformations can be used in design of optical and fluorescent chemosensors.

作者简介

E. Shepelenko

Federal Research Centre the Southern Scientific Centre of the Russian Academy of Sciences

V. Podshibyakin

Institute of Physical and Organic Chemistry, Southern Federal University

I. Dubonosova

Institute of Physical and Organic Chemistry, Southern Federal University

O. Karlutova

Institute of Physical and Organic Chemistry, Southern Federal University

A. Dubonosov

Federal Research Centre the Southern Scientific Centre of the Russian Academy of Sciences

Email: aled@ipoc.sfedu.ru

V. Bren

Institute of Physical and Organic Chemistry, Southern Federal University

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