Heteroleptic Zinc Catecholate Complexes with N-Donor Ligands

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Abstract

New heteroleptic zinc catecholate complexes based on 3,6-di-tert-butyl-o-benzoquinone and containing metal-coordinated N-donor ligands (2,2'-bipyridine and phenanthroline) were prepared by ligand exchange. According to X-ray diffraction data, both complexes were dimers with multiple intermolecular π–π interactions between the aromatic moieties of neighboring molecules (CCDC nos. 2222704 (I), 2222705 (II)). The electronic transmission spectra of crystalline samples of I and II and their solutions show broad absorption bands in the visible region with a maximum at about 500 nm.

About the authors

A. V. Maleeva

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: arina@iomc.ras.ru
Россия, Нижний Новгород

O. Yu. Trofimova

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: pial@iomc.ras.ru
Россия, Нижний Новгород

I. A. Yakushev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: pial@iomc.ras.ru
Россия, Москва

R. R. Aysin

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

Email: pial@iomc.ras.ru
Россия, Москва

A. V. Piskunov

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Author for correspondence.
Email: pial@iomc.ras.ru
Россия, Нижний Новгород

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Copyright (c) 2023 А.В. Малеева, О.Ю. Трофимова, И.А. Якушев, Р.Р. Айсин, А.В. Пискунов