Crystal Structure of Lanthanide Salts with 2,4-Dichlorophenoxyacetic Acid

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

Compounds of three types, [LnL3(C2H5OH)] (Ln = Nd (I), Sm (II), Eu (III)), [LnL3(H2O)] (Ln = = Gd (IV), Tb (V)), and [DyL2(NO3)(C2H5OH)2] (VI), were obtained by reactions of lanthanide nitrate with NaL (L– = 2,4-dichlorophenoxyacetate anion) in ethanol. The composition and structure of complexes I–VI were investigated by elemental and thermogravimetric analysis, IR spectroscopy, and X-ray diffraction (nos. 2311578 (I), 2311579 (II), 2311580 (III) 2311581 (IV), 2311582 (VI)). All compounds have a one-dimensional polymer structure in which metal atoms are connected by bridging carboxylate groups. The π–π interactions and intermolecular contacts between the chains give rise to a three-dimensional supramolecular structure.

Full Text

Restricted Access

About the authors

M. A. Kiskin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: shuvic@gmail.com
Russian Federation, Moscow

O. V. Konnik

Vernadsky Crimea Federal University

Email: shuvic@gmail.com
Russian Federation, Simferopol

V. F. Shulgin

Vernadsky Crimea Federal University

Author for correspondence.
Email: shuvic@gmail.com
Russian Federation, Simferopol

A. N. Gusev

Vernadsky Crimea Federal University

Email: shuvic@gmail.com
Russian Federation, Simferopol

References

  1. Hou S.L., Dong J., Tang M.H. et al. // Anal. Chem. 2019. V. 91. P. 5455.
  2. Wen G.X., Wu Y.P., Dong W.W. et al. // Inorg. Chem. 2016. V. 55. P. 10114.
  3. Yan W., Wang L., Yangxiao K. et al. // Dalton Trans. 2016. V. 45. P. 4518.
  4. Wei J.H., Yi J.W., Han M.L. et al. // Chem. Asian J. 2020. V. 14. P. 3694.
  5. Zeng M.H., Yin Z., Tan Y.X. et al. // J. Am. Chem. Soc. 2014. V. 136. P. 4680.
  6. Zhou L.J., Deng W.H., Wang Y.L. et al. // Inorg. Chem. 2016. V. 55. P. 6271.
  7. Kim T.H., White A.R., Sirdaarta J.P. et al. // ACS Appl. Mater. Interfaces. 2016. V. 8. P. 33102.
  8. Chen D., Xu W., Zhou Y. et al. // J. Mater. Chem. C. 2017. V. 5. P. 738.
  9. Fan Y., Guo X., Zhang Y. et al. // ACS Appl. Mater. Interfaces. 2016. V. 8. P. 31863.
  10. Ji W.-Q., Zhang Q.-H., Wang C.-F. et al. // Ind. Eng. Chem. Res. 2016. V. 55. P. 11700.
  11. Shang M., Li C., Lin J. // Chem. Soc. Rev. 2014. V. 43. P. 1372.
  12. Zhao D., Rao X., Yu J. et al. // Inorg. Chem. 2015. V. 54. P. 11193.
  13. Andres J., Hersch R.D., Moser J.-E. et al. // Adv. Funct. Mater. 2014. V. 24. P. 5029.
  14. De Bastiani M., Saidaminov M., Dursun I. et al. // Chem. Mater. 2017. V. 29, P. 3367.
  15. Lin J., Lai M., Dou L. et al. // Nat. Mater. 2018. V. 17. P. 261.
  16. Kang X.M., Hu H.S., Wu Z.L. et al. // Angew. Chem., Int. Ed. 2019. V. 58. P. 16610.
  17. D´Andrade B.W., Forrest S.R. // Adv. Mater. 2004. V. 16. P. 1585.
  18. Ouchi A., Suzuki Y., Ohki Y., Koizumi Y. // Coord. Chem. Rev. 1988. V. 92. P. 29.
  19. Smith G., Kennard C.H.L., White A.H. // J. Chem. Soc. Perkin Trans. 2. 1976. № 7. P. 791.
  20. Dendrinou-Samara C., Drosou D., Iordanidis L. et al. // J. Inorg. Biochem. 2002. V. 92. P. 156.
  21. Guo J., Liang W.J., Song W.D. // Acta Crystallogr. E. 2007. V. 63. P. 1595.
  22. Shi S.M., Chen Z.F., Liu L. // J. Coord. Chem. 2008. V. 61. P. 2725.
  23. Ma D., Qin L., Zhao H. et al. // Synthetic Metals. 2012. V. 162. P. 2282.
  24. Ma D., Lu K., Guo H. et al. // J. Mol. Struct. 2012. V. 1021. P. 179.
  25. Gusev A.N., Konnik O.V., Shul´gin V.F et al. // Polyhedrone. 2023. 116749.
  26. SMART (control) and SAINT (integration) Sofware. Version 5.0. Madison (WI, USA): Bruker AXS Inc., 1997.
  27. Krause L., Herbst-Irmer R., Stalke D. // J. Appl. Crystallogr. 2015. V. 48. P. 1907.
  28. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3.
  29. Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Cryst. 2015. V. 42. P. 339.
  30. Ruiz-Martínez A., Casanova D., Alvarez S. // Chem. Eur. J. 2008. V. 14. P. 1291.
  31. Nakamoto K. Infrared and RamanSpectra of Inorganic and Coordination Compounds. Pt A: Theory and Applicationsin Inorganic Chemistry. Hoboken (New Jersey): John Wiley & Sons, Inc., 2009. P. 183.

Supplementary files

Supplementary Files
Action
1. JATS XML
Download
2. Fig. 1. Centrosymmetric dimeric fragment of the polymer chain in III (different ways of coordination of carboxylate anion are shown)

Download (151KB)
Indexing metadata
3. Fig. 2. Fragment of the polymer chain in IV (different ways of coordination of carboxylate anion are shown)

Download (179KB)
Indexing metadata
4. Fig. 3. Fragment of the polymer chain in VI

Download (191KB)
Indexing metadata
5. Fig. 4. Fragment of crystal packing II (carbon atoms of benzene rings bound by π...π- interactions are numbered)

Download (272KB)
Indexing metadata
6. Fig. 5. Fragment of crystal packing IV (carbon atoms of benzene rings bound by π...π- interactions are numbered)

Download (298KB)
Indexing metadata
7. Fig. 6. Fragment of crystal packing VI (carbon atoms of benzene rings bound by π...π- interactions are numbered)

Download (482KB)
Indexing metadata

Copyright (c) 2024 Российская академия наук