3,6-Dipyridyl-1,2,4,5-tetrazine in the Synthesis of Zinc and Cadmium Metal-Organic Frameworks with Anilate-Type Ligands

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Abstract

New heteroleptic metal-organic frameworks (MOF) of zinc (3D MOF) and cadmium (2D MOF) are prepared by the two-stage synthesis: [Zn(pQ)(DPT)]·2DMF (I) and Cd2(NO3)2-(pQ)(DPT)3]·2DMF·2MeOH (II), where pQ is the 2,5-dihydroxy-3,6-di-tert-butyl-para-benzoquinone dianion, DPT is 3,6-di(pyridin-4-yl)-1,2,4,5-tetrazine, and DMF is N,N-dimethylformamide (DMF). The structures of the compounds are studied by XRD (CIF files CCDC nos. 2332754 (I) and 2332755 (II)). The thermal stability of the MOF is studied by thermogravimetry.

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About the authors

O. Yu. Trofimova

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: olesya@iomc.ras.ru
Russian Federation, Nizhny Novgorod

D. S. Kolevatov

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: olesya@iomc.ras.ru
Russian Federation, Nizhny Novgorod

N. O. Druzhkov

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: olesya@iomc.ras.ru
Russian Federation, Nizhny Novgorod

A. V. Maleeva

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: olesya@iomc.ras.ru
Russian Federation, Nizhny Novgorod

I. A. Yakushev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: olesya@iomc.ras.ru
Russian Federation, Moscow

P. V. Dorovatovskii

National Research Center Kurchatov Institute

Email: olesya@iomc.ras.ru
Russian Federation, Moscow

A. V. Piskunov

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: olesya@iomc.ras.ru
Russian Federation, Nizhny Novgorod

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Supplementary files

Supplementary Files
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2. Scheme 1: Organic ligands used for the synthesis of zinc and cadmium MOCPs.

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3. Scheme 2: Synthesis of heteroleptic MOCPs I and II.

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4. Fig. 1. Molecular structure of the link and polyhedron of MOCP I. Thermal ellipsoids are given at 50% probability. Hydrogen atoms and “guest” DMF molecules are not depicted.

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5. Fig. 2. Molecular structure of the link and polyhedron of MOCP II. Thermal ellipsoids are given at 50% probability. Hydrogen atoms and “guest” molecules of DMF and MeOH are not depicted.

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6. Fig. 3. View of the MOCP I framework along vector (001) (a); location of interpenetrating MOCP I frameworks in the crystal along vector (001) (b); view of channels in I along vector (001) (c). The outer side of the channels is pink; the inner side is blue. “Guest” DMF molecules are not depicted.

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7. Fig. 4. View of a pair of interpenetrating MOCP II networks along vector (100) (a); layers formed by pairwise interpenetrating networks in the crystal along vector (010) (b); view of pores in II along vector (010) (c). The outer side of the pores is pink; the inner side is blue. “Guest” molecules of DMF and MeOH are not depicted.

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8. Fig. 5. Thermogravimetric curves for MOC I (red line) and II (blue line).

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