Neutral Terbium(III) Tris(complex) with 4,4,5,5,6,6,6-Heptafluoro-1-(1-methyl-1H-pyrazol-4-yl)hexane-1,3-dione: Synthesis, Structure, and Spectral Luminescence Properties

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅存取

详细

The reaction of 1,3-diketone containing 1-methyl-1H-pyrazol-4-yl and perfluoropropyl fragments with TbCl3·6H2O in the presence of NaOH in ethanol is studied. The molecular and crystal structures of the complex are studied by single-crystal X-ray diffraction (XRD). Compound [Tb(L)3(EtOH)2] crystallizes in the triclinic crystal system with the space group. The geometry of the coordination polyhedron {LnO8} corresponds to a square antiprism. Intermolecular interactions N…H–O, C–H…O, and C–H…F leading to the formation of supramolecular chains are observed in crystals of the complex. The UV-irradiated complex exhibits green luminescence caused by transitions 5D4 → 7Fj (j = 2–6) characteristic of the Tb3+ ion. The main photophysical luminescence parameters are determined, and the scheme of energy transfer in the complex is proposed. The synthesized compound can be of interest as an independent luminophore or as the initial substance for the synthesis of heteroligand complexes by the substitution of ethanol molecules in the internal coordination sphere.

全文:

受限制的访问

作者简介

I. Taidakov

Lebedev Physical Institute, Russian Academy of Sciences; National Research Institute Higher School of Economics; Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: taidakov@gmail.com
俄罗斯联邦, Moscow; Moscow; Moscow

M. Metlin

Lebedev Physical Institute, Russian Academy of Sciences

Email: taidakov@gmail.com
俄罗斯联邦, Moscow

D. Metlina

Lebedev Physical Institute, Russian Academy of Sciences

Email: metlinada@lebedev.ru
俄罗斯联邦, Moscow

V. Goncharenko

Lebedev Physical Institute, Russian Academy of Sciences; National Research Institute Higher School of Economics

Email: taidakov@gmail.com
俄罗斯联邦, Moscow; Moscow

T. Vlasova

Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences

Email: taidakov@gmail.com
俄罗斯联邦, Moscow

参考

  1. Costa I.F., Blois L., Paolini T.B. et al. // Coord. Chem. Rev. 2024. V. 502. P. 215590. https://doi.org/10.1016/j.ccr.2023.215590
  2. Saloutin V.I., Edilova Y. O., Kudyakova Y. S. et al. // Molecules. 2022. V. 27. № 22. P. 7894. https://doi.org/10.3390/molecules27227894
  3. De Sa G.F., Malta O. L., de Mello Donegá C. et al. // Coord. Chem. Rev. 2000. V. 196. № 1. P. 165. https://doi.org/10.1016/S0010-8545(99)00054-5
  4. Chauhan A., Kumar A., Singh G. et al. // J. Rare Earths. 2024. V. 42. № 1. P. 16. https://doi.org/10.1016/j.jre.2023.02.006
  5. Wu A., Huo P., Yu G. et al. // Adv. Opt. Mater. 2022. V. 10. № 22. P. 2200952. https://doi.org/10.1002/adom.202200952
  6. Ilmi, R., Kansız, S., Dege, N., Khan, M.S. // J. Photochem. Photobiol. A. 2019. V. 377. P. 268. https://doi.org/10.1016/j.jphotochem.2019.03.036
  7. Bryleva Y.A., Arteme′v A.V., Glinskaya L.A. et al. // New J. Chem. 2021. V. 45. № 31. P. 13869. https://doi.org/10.1039/D1NJ02441H
  8. Gontcharenko V.E., Lunev A.M., Taydakov I.V. et al. // IEEE Sens. J. 2019. V. 19. № 17. P. 7365–7372. https://doi.org/10.1109/JSEN.2019.2916498
  9. Zairov R.R., Shamsutdinova N. А., Fattakhova А. N. et al. // Russ. Chem. Bull. 2016. V. 65. P. 1325–1331. https://doi.org/10.1007/s11172-016-1456-2
  10. Jia Y., Wang J., Zhao L., Yan B. // Talanta. 2022. V. 236. P. 122877. https://doi.org/10.1016/j.talanta.2021.122877
  11. Lyubov D.M., Neto A.N.C., Fayoumi A. et al. // J. Mater. Chem. C. 2022. V. 10. № 18. P. 7176. https://doi.org/10.1039/d2tc01289h
  12. Pavlov D.I, Yu X., Ryadun A.A. et al. // Food Chem. 2024. P. 138747. https://doi.org/10.1016/j.foodchem.2024.138747
  13. Wang L., Shi C., Zhang C. et al. // Adv. Mater Technol. 2021. V. 6. № 8. P. 2100078. https://doi.org/10.1002/admt.202100078
  14. Yu X., Ryadun A.A., Pavlov D.I. et al. // Adv. Mater. 2024. P. 2311939. https://doi.org/10.1002/adma.202311939
  15. de Azevedo L.A., Gamonal A., Maier-Queiroz R. et al. // J. Mater. Chem. C. 2021. V. 9. № 29. P. 9261–9270. https://doi.org/10.1039/d1tc01357b
  16. Korshunov V.M., Metlina D. A., Kompanets V. O. et al. // Dyes and Pigments. 2023. V. 218. P. 111474. https://doi.org/10.1016/j.dyepig.2023.111474
  17. de Oliveira T.C., de Lima J.F., Colaço M.V. et al. // J. Lumin. 2018. V. 194. P. 747. https://doi.org/10.1016/j.jlumin.2017.09.046
  18. Ilmi R., Iftikhar K. // J. Photochem. Photobiol. A. 2017. V. 333. P. 142. https://doi.org/10.1016/j.jphotochem.2016.10.014
  19. Varaksina E.A., Taydakov I.V., Ambrozevich S.A. et al. // J. Lumin. 2018. V. 196. P. 161. https://doi.org/10.1016/j.jlumin.2017.12.006
  20. Varaksina E.A., Kiskin M.A., Lyssenko K A. et al. // Phys. Chem. Chem. Phys. 2021. V. 23. №. 45. P. 25748. https://doi.org/10.1039/d1cp02951g
  21. Taydakov I.V., Krasnoselsky S.S. // Chem. Heterocycl. Compd. 2011. V. 47. P. 695. https://doi.org/10.1007/s10593-011-0821-1
  22. Sheldrick G.M. SADABS. Program for Scaling and Correction of Area Detector Data. Germany: Univ. of Göttingen., 1997.
  23. Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. P. 3. http://doi.org/10.1107/S2053273314026370
  24. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3. http://doi.org/10.1107/S2053229614024218
  25. Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Crystallogr. 2009. V. 42. P. 339. https://doi.org/10.1107/S0021889808042726
  26. Metlin M.T., Belousov Y.A., Datskevich N.P. et al. // Russ. Chem. Bull. 2022. V. 71. № 10. P. 2187. https://doi.org/10.1007/s11172-022-3645-5
  27. Taidakov I.V., Lobanov A.N., Vitukhnovskii A.G. et al. // Russ. J. Coord. Chem. 2013. V. 39. P. 437. https://doi.org/10.1134/S1070328413050072
  28. Taidakov I.V., Vitukhnovskii A.G., Nefedov S.E. // Russ. J. Inorg. Chem. 2013. V. 58. № 7. P. 783. https://doi.org/10.1134/S0036023613070218
  29. Metlina D.A., Metlin M.T., Ambrozevich S.A. et al. // Dyes Pigments. 2020. V. 181. P. 108558. https://doi.org/10.1016/j.dyepig.2020.108558
  30. Metlin M.T., Goryachii D.O., Aminev D.F. et al. // Dyes Pigments. 2021. V. 195. P. 109701. https://doi.org/10.1016/j.dyepig.2021.109701
  31. Petrov A.I., Lutoshkin M.A., Taydakov I.V. // Eur. J. Inorg. Chem. 2015. V. 2015. № 6. P. 1074. https://doi.org/10.1002/ejic.201403052
  32. Carnall W.T., Crosswhite H., Crosswhite H.M. Energy level structure and transition probabilities in the spectra of the trivalent lanthanides in LaF₃. Argonne, IL (United States): Argonne National Lab., 1978.
  33. Bünzli J.C.G., Eliseeva S.V. // Lanthanide luminescence: photophysical, analytical and biological aspects. Springer Series on Fluorescence. V. 7. Berlin; Heidelberg: Springer, 2011. P. 1. https://doi.org/10.1007/4243_2010_3

补充文件

附件文件
动作
1. JATS XML
下载
2. Scheme 1: Synthesis of complex I.

下载 (83KB)
索引源数据
3. Fig. 1. Molecular structure of compound I. The ellipsoids of thermal vibrations of atoms are given with 50% probability, hydrogen atoms are not represented. The perfluorinated substituents of the -diketonate ligand are depicted as translucent. The atoms of terbium and its coordination environment are numbered.

下载 (199KB)
索引源数据
4. Fig. 2. System of hydrogen and ... interactions stabilizing the crystal packing of compound I. Hydrogen bonds are depicted by dotted lines, the shortest distance between π-systems is depicted by a dashed line. Only hydrogen atoms of hydroxyl groups of ethanol molecules are represented, and perfluorinated substituents of -diketonate ligand are depicted as translucent.

下载 (265KB)
索引源数据
5. Fig. 3. Absorption spectra of solutions of complex I (black line) and free ligand HL (red line) in acetonitrile recorded at room temperature.

下载 (81KB)
索引源数据
6. Fig. 4. Excitation spectrum of complex I in the crystalline phase recorded at room temperature. The registration wavelength is 545 nm.

下载 (89KB)
索引源数据
7. Fig. 5. Luminescence spectra of complex I in the crystalline phase at 77 K (black line) and 300 K (red line). The excitation source wavelength is 355 nm.

下载 (111KB)
索引源数据
8. Fig. 6. Color diagram (CIE 1931 color space) for complex I emission.

下载 (136KB)
索引源数据
9. Fig. 7. Fluorescence (red line) at 300K and phosphorescence (black line) spectra at 77K for complex II in the crystalline phase. The excitation wavelength is 355 nm.

下载 (109KB)
索引源数据
10. Fig. 8. Luminescence kinetics of complex I in the crystalline phase at 77 and 300 K. The excitation wavelength is 355 nm.

下载 (110KB)
索引源数据
11. Fig. 9. Energy diagram of complex I and possible pathways of excitation energy transfer in this complex.

下载 (186KB)
索引源数据

版权所有 © Российская академия наук, 2024