Synthesis and Structure of Manganese Complexes with N,N’-bis[(2,4,6-trimethylphenyl)imino]acenaphthene

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Дәйексөз келтіру

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Аннотация

Methods for the synthesis of new manganese(II) complexes with N,N’-bis[(2,4,6-trimethylphenyl) imino (acenaphthene (Tmp-bian), [Mn(Tmp-bian)Br2] (I), [Mn(Tmp-bian)(EtOH)Br2] (Ia), [Mn(Tmpbian) Cl2] (II), [Mn(Tmp-bian)2 (ClO4) 2] (III), and [Mn(Tmp-bian)2(OTs)2] (IV) were developed. The obtained compounds were characterized by elemental analysis and IR spectroscopy. The molecular structures of I, Iа, and III were determined by X-ray diffraction (CCDC no. 233510–233512). The electronic structures of I and III were established by quantum chemical calculations using density functional theory (DFT).

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Авторлар туралы

Yu. Laricheva

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: nikolaj.romashev75@gmail.com
Ресей, Novosibirsk

Ch. Guan

Novosibirsk National Research State University

Email: nikolaj.romashev75@gmail.com
Ресей, Novosibirsk

N. Kuratieva

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: nikolaj.romashev75@gmail.com
Ресей, Novosibirsk

N. Romashev

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: nikolaj.romashev75@gmail.com
Ресей, Novosibirsk

A. Gushchin

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: nikolaj.romashev75@gmail.com
Ресей, Novosibirsk

Әдебиет тізімі

  1. Kallmeier F., Kempe R. // Angew. Chem. Int. Ed. 2018. V. 57. № 1. P. 46.
  2. Najafpour M. M., Allakhverdiev S. I. // Int. J. Hydrogen Energy. 2012. V. 37. № 10. P. 8753.
  3. Mallick Ganguly O., Moulik S. // Dalton Trans. 2023. V. 52. № 31. P. 10639.
  4. Vinogradova K. A., Shekhovtsov N. A., Berezin A. S. et al. // Inorg. Chem. Commun. 2019. V. 100. P. 11.
  5. Berezin A.S., Vinogradova K.A., Nadolinny V.A. et al. // Dalton Trans. 2018. V. 47. № 5. P. 1657.
  6. Artem’Ev A.V., Davydova M.P., Berezin A.S. et al. // ACS Appl. Mater. Interfaces. 2022. V. 14. № 27. P. 31000.
  7. Davydova M. ., Bauer I.A., Brel V.K. et al. // Eur. J. Inorg. Chem. 2020. V. 2020. № 8. P. 695–703.
  8. Artem’ev A.V., Davydova M.P., Rakhmanova M.I. et al. // Inorg. Chem. Front. 2021. V. 8. № 15. P. 3767.
  9. Artem’ev A.V., Kashevskii A.V., Bogomyakov A.S. et al. // Dalton Trans. 2017. V. 46. № 18. P. 5965.
  10. Hu J. Q., Song E. H., Ye S. et al // J. Mater. Chem. C. 2017. V. 5. № 13. P. 3343.
  11. Zou S., Liu Y., Li J. et al. // J. Am. Chem. Soc. 2017. V. 139. № 33. P. 11443.
  12. Davydova M., Meng L., Rakhmanova M.I. et al. // Adv. Mater. 2023. V. 35. № 35. P. 2303611.
  13. Qin Y., She P., Huang X., Huang W. et al. // Coord. Chem. Rev. 2020. V. 416. P. 213331
  14. van Asselt R., Gielens E.E.C.G., Rülke R.E. et al. // J. Am. Chem. Soc. 1994. V. 116. № 3. P. 977.
  15. Fomenko I.S., Romashev N.F., Gushchin. A.L. // Coord. Chem. Rev. 2024. V. 514. P. 215845.
  16. Fedushkin I.L., Skatova A.A., Chudakova V.A. et al. // Angew. Chem. Int. Ed. 2003. V. 42. № 28. P. 3294.
  17. Bernauer J., Pölker J., Jacobi von Wangelin A. // ChemCatChem. 2022. V. 14. № 1. Art. e202101182.
  18. Fomenko I.S., Koshcheeva O.S., Kuznetsova N.I. et al. // Catalysts. 2023. V. 13. № 5. P. 849.
  19. Fomenko I. S., Gongola M. I., Shul’pina L. S. et al. // Catalysts. 2022. V. 12. № 10. P. 1168.
  20. Komlyagina V.I., Romashev N.F., Kokovkin V. et al. // Molecules. 2022. V. 27. № 20. P. 6961.
  21. Komlyagina V.I., Romashev N.F., Besprozvannykh V.K. et al. // Inorg. Chem. 2023. V. 62. № 29. P. 11541.
  22. Romashev N.F., Abramov P.A., Bakaev I. et al. // Inorg. Chem. 2022. V. 61. № 4. P. 2105.
  23. Hasan K., Zysman-Colman E. // Inorg. Chem. 2012. V. 51. № 22. P. 12560.
  24. Geary E.A.M., Yellowlees L.J., Jack L.A. et al. // Inorg. Chem. 2005. V. 44. № 2. P. 242.
  25. Bakaev I.V., Romashev N.F., Komlyagina V.I. et al. // New J. Chem. 2023. V. 47. № 40. P. 18825.
  26. Schmiege B.M., Carney M.J., Small B.L. et al. // Dalton Trans. 2007. № 24. P. 2547.
  27. Zhou M., Li X., Bu D.et al. // Polyhedron. 2018. V. 148. P. 88.
  28. Carrington S.J., Chakraborty I., Mascharak P.K. // Dalton Trans. 2015. V. 44. № 31. P. 13828.
  29. Fedushkin I.L., Sokolov V.G., Makarov V.M. et al. // Russ. Chem. Bull. 2016. V. 65. № 6. P. 1495.
  30. Bermejo M.R., Perez M.C., Fondo M. et al. // Synth. React. Inorg. Met. Chem. 1997. V. 27. № 7. P. 1009.
  31. Girolami G.S. // Inorg. Synth. 2002. V. 33. P. 91.
  32. El-Ayaan U., Murata F., El-Derby S. et al. // J. Mol. Struct. 2004. V. 692. № 1–3. P. 209.
  33. te Velde G., Bickelhaup, F.M., Baerends E.J. et al. // J. Comput. Chem. 2001. V. 22. № 9. P. 931.
  34. Van Lenthe E., Baerends E.J. // J. Comput. Chem. 2003. V. 24. № 9. P. 1142.
  35. Van Lenthe E., Snijders J.G., Baerends E.J. // J. Chem. Phys. 1996. V. 105. № 15. P. 6505.
  36. APEX2 (version 2.0), SAINT (version 8.18c), and SADABS (version 2.11), Bruker Advanced X-ray Solutions. Madison (WI, USA): Bruker AXS Inc., 2000–2012.
  37. Bruker Apex3 software suite: Apex3, SADABS-2016/2 and SAINT, version 2019.1-0; Bruker AXS Inc.: Madison, WI, 2017.
  38. Sheldrick G.M. SADABS. Program for Scaling and Correction of Area Detector Data. Göttingen (Germany): Unive. of Göttingen, 1996.
  39. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. № 1. P. 3.
  40. Singh G., Kapoor I.P.S., Kumar D. et al. // Inorg. Chim. Acta. 2009. V. 362. № 11. P. 4091.

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Әрекет
1. JATS XML
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2. Scheme 1. Synthesis of Mn/BIAN complexes

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3. Scheme 2. Synthesis of Mn/BIAN organometallic complexes

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4. Scheme 3

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5. Scheme 4. Synthesis of manganese complexes I-IV

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6. Fig. 1. Molecular structure of complexes I and Ia according to PCA data. The insets show the selected angles of the Mn-Br(2)-N(2) (left) and Mn-Br(2)-N(2)-O (right) coordination unit. Hydrogen atoms are omitted for clarity

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7. Fig. 2. Molecular structure of complex III according to PCA data (a); selected angles of the Mn-N(2)-O(2) coordination unit (b). Hydrogen atoms are not shown

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8. Fig. 3. General view and energy levels of the boundary orbitals for the ground state of complex I. VZMO, VZMO-1, VZMO-2, VZMO-3, NSMO, NSMO+1 are shown

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9. Fig. 4. General view and energy levels of the boundary orbitals for the ground state of complex III. VZMO, VZMO-1, VZMO-2, VZMO-3, NSMO, NSMO+1 are shown

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