Regularities of establishing of thermal regimes in countercurrent plug reactor

N. G. Samoilenko; Самойленко Н. Г.; K. G. Shkadinskiy; Шкадинский К. Г.; E. N. Shatunova; Шатунова Е. Н.; B. L. Korsunskiy; Корсунский Б. Л.

doi:10.31857/S0207401X24120053

Regularities of establishing of thermal regimes in countercurrent plug reactor

Authors: Samoilenko N.G.¹, Shkadinskiy K.G.¹, Shatunova E.N.¹, Korsunskiy B.L.¹
Affiliations:
1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Issue: Vol 43, No 12 (2024)
Pages: 53-60
Section: Kinetics and mechanism of chemical reactions, catalysis
URL: https://cardiosomatics.ru/0207-401X/article/view/684177
DOI: https://doi.org/10.31857/S0207401X24120053
ID: 684177

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Abstract
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About the authors
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Abstract

For a countercurrent liquid–liquid plug reactor, theoretical studies of the implementation of possible types of stationary states were carried out. States such as a stable node and focus, and an unstable focus with a stable limit cycle (oscillations) have been discovered. Using these data, the evolution of stationary states with continuous changes in external control parameters was studied. When the relationship between the flow rates of the phases changes, a structure of stationary states is discovered, which can be realized both at the entrance and exit of the dispersion medium.

Keywords

countercurrent reactor, heterogeneous system, exothermic reaction, mathematical modeling, oscillations

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About the authors

N. G. Samoilenko

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: shale@icp.ac.ru
Russian Federation, Chernogolovka

K. G. Shkadinskiy

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: shale@icp.ac.ru
Russian Federation, Chernogolovka

E. N. Shatunova

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: shale@icp.ac.ru
Russian Federation, Chernogolovka

B. L. Korsunskiy

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: shale@icp.ac.ru
Russian Federation, Chernogolovka

References

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N.G. Samoilenko, E.N. Shatunova, K.G. Shkadinsky, B.L. Korsunsky, L.V. Kustova. Russ. J. Phys. Chem. B 15, 833 (2021). https://doi.org/10.1134/S1990793121040230
V.I. Kovenskii. Theor. Found. Chem. Eng. 50, 1015 (2016). https://doi.org/10.1134/S0040579516040382
N.G. Samoilenko, E.N. Shatunova, K.G. Shkadinskiy, B.L. Korsunskiy. Russ. J. Phys. Chem. B 16, 1130 (2022). https://doi.org/10.1134/S1990793122060203

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2. Fig. 1. Dynamics of thermal regimes and coordinates of the maximum temperature of the dispersion medium depending on the parameter Um at S1 = 0.2.

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3. Fig. 2. Characteristic phase trajectories of the reactor reaching the thermal mode at S1 = 0.2: a – node, Um = 0.037; b – stable focus, Um = 0.041; c – oscillatory mode, Um =0.05.