Effect of the Composition and Synthesis Procedure of the Catalysts Based on the CoAl-Hydroxides on their Properties in Furfural Hydrogenation

E. О. Kobzar; Кобзарь Е. О.; L. N. Stepanova; Степанова Л. Н.; N. N. Leont’eva; Леонтьева Н. Н.; T. I. Gulyaeva; Гуляева Т. И.; M. V. Trenikhin; Тренихин М. В.; A. V. Lavrenov; Лавренов А. В.

doi:10.31857/S0453881123040056

Effect of the Composition and Synthesis Procedure of the Catalysts Based on the CoAl-Hydroxides on their Properties in Furfural Hydrogenation

Autores: Kobzar E.О.¹, Stepanova L.N.¹, Leont’eva N.N.¹, Gulyaeva T.I.¹, Trenikhin M.V.¹, Lavrenov A.V.¹
Afiliações:
1. Center of New Chemical Technologies, Boreskov Institute of Catalysis
Edição: Volume 64, Nº 4 (2023)
Páginas: 474-485
Seção: 7-я Международная школа-конференция молодых ученых “Катализ: от науки к промышленности”
URL: https://cardiosomatics.ru/0453-8811/article/view/660323
DOI: https://doi.org/10.31857/S0453881123040056
EDN: https://elibrary.ru/RQUMCJ
ID: 660323

Citar

Texto integral

Acesso aberto
Acesso é fechado

Acesso está concedido
Acesso é fechado

Acesso é pago ou somente para assinantes

Resumo
Sobre autores
Bibliografia
Arquivos suplementares
Estatísticas

Resumo

CoAl-hydroxides with Co/Al = 2 and 4 were synthesized by traditional coprecipitation method and mechanochemical route. Structure properties of the samples on the all preparation stages of the catalysts, the transformations occurred during cobalt reduction from corresponding oxides, textural characteristics of calcined and reduced samples, as well as size, morphology and composition of the particles that formed after high temperature treatments were studied in detailed. It was established, that synthesis procedure of CoAl-hydroxides has a significant impact on phase composition and properties of obtained systems. The phase of layered double hydroxide formed only when using coprecipitation method. The mechanochemical approach allowed to obtained the materials with higher specific surface area. According to TEM data, the samples prepared by coprecipitation (after oxidative and reductive treatments) had a “core-shell” structure where metallic atoms of Co were in core and shell consisted of CoAl-spinel. The samples synthesized by mechanochemical route had Co nanoparticles with high dispersion on the surface. The catalysts based on CoAl-systems prepared by mechanochemical method were more active in the furfural hydrogenation. Conversion of furfural achieved 97% for the sample with Co/Al = 4. Herewith, selectivity of furfural formation for all studied catalysts was almost 100% irrespective of synthesis procedure and Co/Al ratio.

Palavras-chave

CoAl-hydroxides, mixed oxides, mechanochemical method, furfural hydrogenation

Bibliografia

Ekpeni L.E.N., Benyounis K.Y., Nkem-Ekpeni F., Stokes J., Olabi A.G. // Energy Procedia. 2014. V. 61. P. 1740.
Bozell J.J., Petersen G.R. // Green Chem. 2010. V. 12. № 4. P. 539.
Yan K., Wu G., Lafleur T., Jarvis C. // Renew. Sustain. Energy Rev. 2014. V. 38. P. 663.
Mishra D.K., Kumar S., Shukla R.S. // Biomass, Biofuels, Biochemicals. 2020. P. 323.
Bremner J.G.M., Keeys R.K.F. // J. Chem. Soc. 1947. P. 1068.
Fulajtárova K., Soták T., Hronec M., Vávra I., Dobročka E., Omastová M. // Appl. Catal. A. 2015. V. 502. P. 78.
Mironenko R.M., Belskaya O.B., Talsi V.P., Likholobov V.A. // J. Catal. 2020. V. 389. P. 721.
Taylor M.J., Durndell L.J., Isaacs M.A., Parlett C.M.A., Wilson K., Lee A.F., Kyriakou G. // Appl. Catal. B: Env. 2016. V. 180. P. 580.
Bhogeswararao S., Srinivas D. // J. Catal. 2015. V. 327. P. 65.
Audemar M., Ciotonea C., De Oliveira Vigier K., Royer S., Ungureanu A., Dragoi B., Dumitriu E., Jérôme F. // ChemSusChem. 2015. V. 8. № 11. P. 1885.
Jiang P., Li X., Gao W., Wang X., Tang Y., Lan K., Wang B., Li R. // Catal. Commun. 2018. V. 111. P. 6.
Gong W., Chen C., Zhang H., Wang G., Zhao H. // Catal. Sci. Technol. 2018. V. 8. № 21. P. 5506.
Chen X., Li H., Luo H., Qiao M. // Appl. Catal. A: Gen. 2002. V. 233. P. 13.
Srivastava S., Mohanty P., Parikh J.K., Dalai A.K., Amritphale S.S., Khare A.K. // Chin. J. Catal. 2015. V. 36. № 7. P. 933.
Mironenko R.M., Likholobov V.A., Belskaya O.B. // Russ. Chem. Rev. 2022. V. 91. № 1. RCR5017.
Mascolo G., Mascolo M.C. // Micropor. Mesopor. Mater. 2015. V. 214. P. 246.
Sulmonetti T.P., Pang S.H., Claure M.T., Lee S., Cullen D.A., Agrawal P.K., Jones C.W. // Appl. Catal. A: Gen. 2016. V. 517. P. 187.
Bertolini G.R., Jiménez-Gómez C.P., Cecilia J.A., Maireles-Torres P. // Catalysts. 2020. V. 10. № 5. P. 486.
Wu J., Gao G., Li J., Sun P., Long X., Li F. // Appl. Catal. B: Env. 2017. V. 203. P. 227.
Wang T., Hu A., Wang H., Xia Y. // J. Chin. Chem. Soc. 2019. V. 66. № 12. P. 1610.
Shao Y., Wang J., Sun K., Gao G., Li C., Zhang L., Zhang S., Xu L., Hu G., Hu X. // Renew. Energy. 2021. V. 170. P. 1114.
Rudolf C., Dragoi B., Ungureanu A., Chirieac A., Royer S., Nastro A., Dumitriu E. // Catal. Sci. Technol. 2014. V. 4. № 1. P. 179.
Biabani-Ravandi A., Rezaei M., Fattah Z. // Proc. Saf. Environ. Prot. 2013. V. 91. № 6. P. 489.
Степанова Л.Н., Бельская О.Б., Василевич А.В., Леонтьева Н.Н., Бакланова О.Н., Лихолобов В.А. // Кинетика и катализ. 2018. Т. 59. № 4. С. 506. (Stepanova L.N., Belskaya O.B., Vasilevich A.V., Leont’eva N.N., Baklanova O.N., Likholobov V.A. // Kinet. Catal. 2018. V. 59. № 4. P. 521.)
Lee S.-B., Ko E.-H., Park J.Y., Oh J.-M. // Nanomater. 2021. V. 11. № 5. P. 1153.
Bukhtiyarova M.V. // J. Solid State Chem. 2018. V. 269. P. 494.
Tongamp W., Zhang Q., Saito F. // Powder Technol. 2008. V. 185. № 1. P. 43.
Khusnutdinov V.P., Isupov V.P. // Inorg. Mater. 2008. V. 44. № 3. P. 263.
Stepanova L.N., Kobzar E.O., Leont’eva N.N., Gulyaeva T.I., Vasilevich A.V., Babenko A.V., Serkova A.N., Salanov A.N., Belskaya O.B. // J. Alloys Compd. 2021. V. 890. P. 161902.
Wang B., Qu J., Li X., He X., Zhang Q. // J. Am. Ceram. Soc. 2016. V. 99. № 9. P. 2882.
Zhang X., Li S. // Appl. Surf. Sci. 2013. V. 274. P. 158.
Zhu J., Zeng B., Mo L., Jin F., Deng M., Zhang Q. // Appl. Clay Sci. 2021. V. 206. P. 106070.
Ay A.N., Zümreoglu-Karan B., Mafra L. // Z. Anorg. Allg. Chem. 2009. V. 635. № 9. P. 1470.
Teodorescu F., Slabu A.I., Pavel O.D., Zăvoianu R. // Catal. Commun. 2019. V. 133. P. 105829.
Kobzar E.O., Stepanova L.N., Leont’eva N.N., Belskaya O.B. // AIP Conf. Proc. 2020. V. 2310. 030010.
Ferencz Z., Kukovecz Á., Kónya Z., Sipos P., Pálinkó I. // Appl. Clay Sci. 2015. V. 112. P. 94.
Ferencz Z., Szabados M., Ádok-Sipiczki M., Kukovecz Á., Kónya Z., Sipos P., Pálinkó I. // J. Mater. Sci. 2014. V. 49. № 24. P. 8478.
Qu J., He X., Chen M., Huang P., Zhang Q., Liu X. // J. Solid State Chem. 2017. V. 250. P. 1.
Qu J., He X., Li X., Ai Z., Li Y., Zhang Q., Liu X. // RSC Adv. 2017. V. 7. № 50. P. 31466.
Ferencz Z., Szabados M., Varga G., Csendes Z., Kuko-vecz Á., Kónya Z., Carlson S., Sipos P., Pálinkó I. // J. Solid State Chem. 2016. V. 233. P. 236.
Qu J., He X., Chen M., Hu H., Zhang Q., Liu X. // Mater. Chem. Phys. 2017. V. 191. P. 173.
Qu J., He X., Wang B., Zhong L., Wan L., Li X., Song S., Zhang Q. // Appl. Clay Sci. 2016. V. 120. P. 24.
Stepanova L.N., Belskaya O.B., Vasilevich A.V., Gulyaeva T.I., Leont’eva N.N., Serkova A.N., Salanov A.N., Likholobov V.A. // Catal. Today. 2019. V. 357. P. 638.
Stepanova L.N., Belskaya O.B., Baklanova O.N., Vasilevich A.V., Likholobov V.A. // Procedia Eng. 2016. V. 152. P. 672.
Stepanova L.N., Mironenko R.M., Kobzar E.O., Leont’eva N.N., Gulyaeva T.I., Vasilevich A.V., Serkova A.N., Salanov A.N., Lavrenov A.V. // ACS Sustain. Chem. Eng. 2022. V. 3. № 4. P. 400.
Wang Y., Miao Y., Li S., Gao L., Xiao G. // Mol. Catal. 2017. V. 436. P. 128.
Chen X., Li H., Luo H., Qiao M. // Appl. Catal. A. 2002. V. 233. № 1. P. 13.
Arnoldy P., Moulijn J.A. // J. Catal. 1985. V. 93. № 1. P. 38.
Ribet S., Tichit D., Coq B., Ducourant B., Morato F. // J. Solid State Chem. 1999. V. 142. № 2. P. 382.