The method for the vizualization of the dynamics of catalyst transformations based on the results of competing experiments

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Abstract

Present paper demonstrates that relative reactivity estimated under competition of several similar substrates can be applied for the demonstrative visualization of the dynamics of active catalyst in a complex catalytic process. The fundamental advantage of the proposed approach is that the state of an active catalyst can be monitored throughout the catalytic reaction without differentiation of the kinetic data on the concentrations of the substances reacted.

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About the authors

A. A. Kurokhtina

Irkutsk State University

Email: aschmidt@chem.isu.ru

Chemical Department

Russian Federation, K. Marx str., 1, Irkutsk, 664003

E. V. Larina

Irkutsk State University

Email: aschmidt@chem.isu.ru

Chemical Department

Russian Federation, K. Marx str., 1, Irkutsk, 664003

N. A. Lagoda

Irkutsk State University

Email: aschmidt@chem.isu.ru

Chemical Department

Russian Federation, K. Marx str., 1, Irkutsk, 664003

A. F. Schmidt

Irkutsk State University

Author for correspondence.
Email: aschmidt@chem.isu.ru

Chemical Department

Russian Federation, K. Marx str., 1, Irkutsk, 664003

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Supplementary files

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2. Scheme 1. Reactions of Suzuki–Miyaury (a) and Mizoroki–Heka (b) in the words of competing couples. арилгалогенидов.

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3. Scheme 2. The principal reaction scheme of Suzuki-Miyaur and Mizoroki-Heka is in the city овании пары конкурирующих арилгалогенидов.

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4. Scheme 3. Общая схема взимопревращения сосуществующих форм катализатора в Reaction to the collection of arilgalogenids.

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5. Fig. 1. Dependences of the values ​​of the relative reactivity of competing 4-bromoacetophenone and bromobenzene, krel = k4-bromoacetophenone/kbromobenzene, calculated according to equation (7), on the conversion of phenylboronic acid in the Suzuki–Miyaura reaction with varying the nature and loading of the palladium catalyst precursor.

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6. Fig. 2. Dependences of the values ​​of relative reactivity of competing 4-chloroacetophenone and 1,4-dichlorobenzene krel = k4-chloroacetophenone/kdichlorobenzene, calculated according to equation (7), on the conversion of n-butyl acrylate in the Mitsoroki–Heck reaction with varying the nature and loading of the palladium precursor of the catalyst.

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