Neutral Red and Safranin Т in the Photopolymerization of Methyl Methacrylate and Other (Meth)Acrylate Monomers

O. S. Lizyakina; Лизякина О. С.; L. B. Vaganova; Ваганова Л. Б.; D. F. Grishin; Гришин Д. Ф.

doi:10.31857/S2308113923700535

Neutral Red and Safranin Т in the Photopolymerization of Methyl Methacrylate and Other (Meth)Acrylate Monomers

Autores: Lizyakina O.S.¹, Vaganova L.B.¹, Grishin D.F.¹
Afiliações:
1. National Research Lobachevsky State University of Nizhny Novgorod
Edição: Volume 65, Nº 4 (2023)
Páginas: 254-264
Seção: КАТАЛИЗ
URL: https://cardiosomatics.ru/2308-1139/article/view/650879
DOI: https://doi.org/10.31857/S2308113923700535
EDN: https://elibrary.ru/QODPEW
ID: 650879

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Resumo

Features of the polymerization of methyl methacrylate and a number of other (meth)acrylate monomers in the presence of catalytic systems based on phenazine dyes (Neutral Red and Safranin Т) under visible light irradiation are investigated. It is shown that amines of various structure as well as air oxygen affect the kinetic features of polymerization and the molecular weight characteristics of polymers. It is found that polymerization may proceed in the controlled mode up to high conversions at room temperature and a low photocatalyst concentration, among them without preliminary degassing of the reaction medium.

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