Novel Catalysts Based on Magnesium, Aluminum, Nickel and Cobalt Hydroxo Salts for the Carbon Dioxide Conversion of Biogenic Alcohols to Hydrogen-Containing Gases

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Abstract

Catalysts based on alumomagnesium hydroxo salts of hydrotalcite type containing nickel and cobalt ions have been used for the first time for carbon dioxide conversion of biogenic alcohols – ethanol and isobutanol – into hydrogen-containing gases (a mixture of hydrogen and carbon monoxide). At the optimum temperatures of 800–900°C, the hydrogen yield in the conversion of ethanol reaches 77–97%, in the conversion of isobutanol – 80–89%.

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About the authors

A. G. Dedov

Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences; Gubkin Russian State University of Oil and Gas

Email: al57@rambler.ru

Academician of the RAS

Russian Federation, Moscow; Moscow

A. S. Loktev

Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences; Gubkin Russian State University of Oil and Gas

Author for correspondence.
Email: al57@rambler.ru
Russian Federation, Moscow; Moscow

D. A. Chibrikova

Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences

Email: al57@rambler.ru
Russian Federation, Moscow

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2. Fig. 1. Diffractogram of 1.75Ni0.25CoGT powder.

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3. Fig. 2. SEM micrograph (a) and distribution mapping of nickel (b) and cobalt (c) in 1.75Ni0.25CoGT powder.

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4. Fig. 3. Diffractogram of 5NiGT catalyst after use in carbon dioxide conversion of isobutanol at 900°C.

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5. Fig. 4. PEM micrograph of 5NiGT catalyst after use in carbon dioxide conversion of isobutanol at 900°C.

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6. Fig. 5. Mass loss curve during heating in air current of 5NiGT catalyst used in carbon dioxide conversion of isobutanol at 900°C.

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