Novel Catalysts Based on Magnesium, Aluminum, Nickel and Cobalt Hydroxo Salts for the Carbon Dioxide Conversion of Biogenic Alcohols to Hydrogen-Containing Gases

Capa

Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Acesso é pago ou somente para assinantes

Resumo

Catalysts based on alumomagnesium hydroxo salts of hydrotalcite type containing nickel and cobalt ions have been used for the first time for carbon dioxide conversion of biogenic alcohols – ethanol and isobutanol – into hydrogen-containing gases (a mixture of hydrogen and carbon monoxide). At the optimum temperatures of 800–900°C, the hydrogen yield in the conversion of ethanol reaches 77–97%, in the conversion of isobutanol – 80–89%.

Texto integral

Acesso é fechado

Sobre autores

A. Dedov

Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences; Gubkin Russian State University of Oil and Gas

Email: al57@rambler.ru

Academician of the RAS

Rússia, Moscow; Moscow

A. Loktev

Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences; Gubkin Russian State University of Oil and Gas

Autor responsável pela correspondência
Email: al57@rambler.ru
Rússia, Moscow; Moscow

D. Chibrikova

Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences

Email: al57@rambler.ru
Rússia, Moscow

Bibliografia

  1. Liew W.M., Ainirazali N. // Energy Convers. Manage. 2025. V. 326. 119463. https://doi.org/10.1016/j.enconman.2024.119463
  2. Dedov A.G., Karavaev A.A., Loktev A.S., Osipov A.K. // Petrol. Chem. 2021. V. 61. P. 1139–1157. https://doi.org/10.1134/S0965544121110165
  3. Zlotin S.G., Egorova K.S., Ananikov V.P., Akulov A.A., Varaksin M.V., Chupakhin O.N., Charushin V.N., Bryliakov K.P., Averin A.D., Beletskaya I.P., Dolengovski E.L., Budnikova Yu.H., Sinyashin O.G., Gafurov Z.N., Kantyukov A.O., Yakhvarov D.G., Aksenov A.V., Elinson M.N., Nenajdenko V.G., Chibiryaev A.M., Nesterov N.S., Kozlova E.A., Martyanov O.N., Balova I.A., Sorokoumov V.N., Guk D.A., Beloglazkina E.K., Lemenovskii D.A., Chukicheva I.Yu., Frolova L.L., Izmest'ev E.S., Dvornikova I.A., Popov A.V., Kutchin A.V., Borisova D.M., Kalinina A.A., Muzafarov A.M., Kuchurov I.V., Maximov A.L., Zolotukhina A.V. // Russ. Chem. Rev. 2023. V. 92. № 12. RCR5104. https://doi.org/10.59761/RCR5104
  4. Aziz M.A.A., Setiabudi H.D., Teh L.P., Annuar N.H.R., Jalil A.A. // J. Taiwan Inst. Chem. Eng. 2019. V. 101. P. 139–158. https://doi.org/10.1016/j.jtice.2019.04.047
  5. Wang W., Wang Y. // Int. J. Hydrogen Energy. 2009. V. 34. P. 5382–5389. https://doi.org/10.1016/j.ijhydene.2009.04.05
  6. Bej B., Bepari S., Pradhan N.C., Neogi S. // Catal. Today. 2017. V. 291. P. 58–66. https://doi.org/10.1016/j.cattod.2016.12.010
  7. Arapova M., Smal E., Bespalko Yu., Fedorova V., Valeev K., Cherepanova S., Ischenko A., Sadykov V., Simonov M. // Int. J. Hydrogen Energy. 2021. V. 46. P. 39236–39250. https://doi.org/10.1016/j.ijhydene.2021.09.197
  8. Ramkiran A., Vo D.-V.N., Mahmud M.S. // Int. J. Hydrogen Energy. 2021. V. 46. P. 24845–24854. https://doi.org/10.1016/j.ijhydene.2021.03.144
  9. Wang M., Li F., Dong J., Lin X., Liu X., Wang D., Cai W. // J. Environ. Chem. Eng. 2022. V. 10. 107892. https://doi.org/10.1016/j.jece.2022.107892
  10. Zhukova A., Fionov Yu., Semenova S., Khaibullin S., Chuklina S., Maslakov K., Zhukov D., Isaikina O., Mushtakov A., Fionov A. // J. Phys. Chem. C. 2024. V. 128. P. 20177–20194. https://doi.org/10.1021/acs.jpcc.4c07213
  11. Wang M., Li T., Tian Y., Zhang J., Cai W. // Catal. Lett. 2024. V. 154. P. 3829–3838. https://doi.org/10.1007/s10562-024-04607-z
  12. Li F., Wang M., Zhang J., Lin X., Wang D., Cai W. // Appl. Catal. A. 2022. V. 638. 118605. https://doi.org/10.1016/j.apcata.2022.118605
  13. Dhanala V., Maity S.K., Shee D. // RSC Adv. 2015. V. 5. P. 52522–52532. https://doi.org/10.1039/C5RA03558A
  14. Dhanala V., Maity S.K., Shee D. // RSC Adv. 2013. V. 3. P. 24521–24529. https://doi.org/10.1039/C3RA44705G
  15. Lee I.C., Clair J.G.St., Gamson A.S. // Int. J. Hydrogen Energy. 2012. V. 37. P. 1399–1408. https://doi.org/10.1016/j.ijhydene.2011.09.121
  16. Chakrabarti R., Kruger J.S., Hermann R.J., Schmidt L.D. // RSC Adv. 2012. V. 2. P. 2527–2533. https://doi.org/10.1039/C2RA01348G
  17. Dhanala V., Maity S.K., Shee D. // J. Ind. Eng. Chem. 2015. V. 27. P. 153–163. https://doi.org/10.1016/j.jiec.2014.12.029
  18. Kruger J.S., Chakrabarti R., Hermann R.J., Schmidt L.D. // Appl. Catal. A. 2012. V. 411–412. P. 87–94. https://doi.org/10.1016/j.apcata.2011.10.023
  19. Sharma M.V.P., Akyurtlu J.F., Akyurtlu A. // Int. J. Hydrogen Energy. 2015. V. 40. P. 13368–13378. https://doi.org/10.1016/j.ijhydene.2015.07.113
  20. Moiseev I.I., Loktev A.S., Shlyakhtin O.A., Mazo G.N., Dedov A.G. // Petrol. Chem. 2019. V. 59. Suppl. 1. P. S1–S20. https://doi.org/10.1134/S0965544119130115
  21. Dedov A.G., Loktev A.S., Danilov V.P., Krasnobaeva O.N., Nosova T.A., Mukhin I.E., Baranchikov A.E., Yorov Kh.E., Bykov M.A., Moiseev I.I. // Petrol. Chem. 2020. V. 60. P. 194–203. https://doi.org/10.1134/S0965544120020048
  22. Qiu Y., Chen J., Zhang J. // Front. Chem. Eng. China. 2007. V. 1. P. 167–171. https://doi.org/10.1007/s11705-007-0031-7
  23. Krasnobaeva O.N., Belomestnykh I.P., Nosova T.A., Kondakov D.F., Elizarova T.A., Danilov V.P. // Russ. J. Inorg. Chem. 2015. V. 60. № 4. P. 409–414. https://doi.org/10.1134/S0036023615040099
  24. de Vasconcelos B.R., Minh D.P., Lyczko N., Phan T.S., Sharrock P., Nzihou A. // Fuel. 2018. V. 226. P. 195–203. https://doi.org/10.1016/j.fuel.2018.04.017
  25. Yuvasravana R., George P.P., Devanna N. // Inter. J. Innovative Res. Sci. Eng. Technol. 2017. V. 6. P. 11256–11265. https://doi.org/10.15680/IJIRSET.2017.0606208

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML
Baixar
2. Fig. 1. Diffractogram of 1.75Ni0.25CoGT powder.

Baixar (129KB)
Metadados
3. Fig. 2. SEM micrograph (a) and distribution mapping of nickel (b) and cobalt (c) in 1.75Ni0.25CoGT powder.

Baixar (754KB)
Metadados
4. Fig. 3. Diffractogram of 5NiGT catalyst after use in carbon dioxide conversion of isobutanol at 900°C.

Baixar (129KB)
Metadados
5. Fig. 4. PEM micrograph of 5NiGT catalyst after use in carbon dioxide conversion of isobutanol at 900°C.

Baixar (124KB)
Metadados
6. Fig. 5. Mass loss curve during heating in air current of 5NiGT catalyst used in carbon dioxide conversion of isobutanol at 900°C.

Baixar (67KB)
Metadados

Declaração de direitos autorais © Russian Academy of Sciences, 2025