The phase composition of Ni1-2хMnхCoхOy precursors, where x = 0–0.5, obtained in the solution combustion synthesis

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The solution combustion synthesis obtained precursors of the composition Ni1–2хMnхCoхOy, where x = 0–0.5. The phase composition of the precursors was confirmed by X-ray phase analysis. The morphology of the samples was studied by scanning electron microscopy in combination with energy dispersion analysis. The change in the phase composition of precursors of mixed d-metal oxides from the synthesis conditions and the choice of annealing temperatures has been studied. The dependences of the content of NiO, Ni, MnCo2O4 in the composition of Ni1–2хMnхCoхOy precursors after SCS, after 550°C were studied. The dependence of the parameter a of the crystal lattice of the spinel phase on the composition of the sample after annealing at 550, 800 and 900°C has been established. Ni1–2хMnхCoхOy with x = 0.1–0.33 is monophase after annealing at 550°C.

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K. Nefedova

The Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences

编辑信件的主要联系方式.
Email: nefedova@ihim.uran.ru
俄罗斯联邦, Pervomaiskaya St., 91, Ekaterinburg, 620990

L. Ermakova

The Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences

Email: nefedova@ihim.uran.ru
俄罗斯联邦, Pervomaiskaya St., 91, Ekaterinburg, 620990

V. Zhuravlev

The Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences

Email: nefedova@ihim.uran.ru
俄罗斯联邦, Pervomaiskaya St., 91, Ekaterinburg, 620990

T. Patrusheva

The Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences

Email: nefedova@ihim.uran.ru
俄罗斯联邦, Pervomaiskaya St., 91, Ekaterinburg, 620990

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2. Fig. 1. Change in the content of phases (wt.%) NiO, Ni and spinel in the composition of precursors Ni1–2xMnxCoxOy depending on the mole fraction (x) of manganese and cobalt: a – after SCS, b – after 550°C.

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3. Fig. 2. Diffraction pattern of the Ni0.7Mn0.15Co0.15Oy sample after SCS.

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4. Fig. 3. Dependences of the parameter a of the crystal lattice of the spinel phase in the composition of Ni1–2хMnхCoхOy on the mole fraction (x) of manganese and cobalt: a – in the two-phase region at 550 and 900°C; b – in the region of solid solutions with a spinel structure at 550 and 900°C.

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5. Fig. 4. Dependences of the parameter a of the crystal lattice of the NiO-based phase in the composition Ni1–2хMnхCoхOy on the mole fraction (x) of manganese and cobalt after annealing at 550, 800 and 900°C (a) and the mass fraction of the NiO-based phase in the composition Ni1–2хMnхCoхOy on the mole fraction (x) of manganese and cobalt after annealing at 550 and 800°C (b).

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6. Fig. 5. Ni0.4Mn0.3Co0.3Oy sample: a – SEM image; b – distribution of Co, Mn and Ni in the sample; c – EDX analysis.

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