Molecular Switches of the LD-CISSS Type Based on Ni(II) Azomethine Bis-Chelate Complexes. Quantum Chemical Modeling
- Авторлар: Kharabayev N.N.1, Starikov A.G.1, Minkin V.I.1
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Мекемелер:
- Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia
- Шығарылым: Том 49, № 8 (2023)
- Беттер: 485-492
- Бөлім: Articles
- URL: https://cardiosomatics.ru/0132-344X/article/view/667490
- DOI: https://doi.org/10.31857/S0132344X23700275
- EDN: https://elibrary.ru/SARRHQ
- ID: 667490
Дәйексөз келтіру
Аннотация
(DFT/B3LYP/6-311++G(d,p)) calculations were performed to study Ni(II) azomethine bis-chelates with photoactive moieties (imidazole and benzimidazole derivatives of azo compounds, azomethines, and stilbenes) exhibiting the behavior of molecular magnetic switches by the light-driven coordination-induced spin state switching (LD-CISSS) mechanism. The structural and energy characteristics of the complexes favorable to or restricting the applicability of these complexes as molecular switches were determined.
Авторлар туралы
N. Kharabayev
Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia
Email: nkharabaev@mail.ru
Россия, Ростов-на-Дону
A. Starikov
Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia
Email: nkharabaev@mail.ru
Россия, Ростов-на-Дону
V. Minkin
Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia
Хат алмасуға жауапты Автор.
Email: nkharabaev@mail.ru
Россия, Ростов-на-Дону
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