Preparation of Water-Soluble Zinc(II) Complexes with Ethylenediaminetetraacetic Acid: Molecular Structure of Zinc Ethylenediaminetetraacetate Trihydrate

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Poorly soluble zinc ethylenediaminetetraacetate zincate Zn[ZnL] reacts with sodium Na4L, potassium K4L, ammonium (NH4)4L, 2-ammonioethanol (H3NCH2CH2OH)4L, and hexamethylene-1,6-diammonium {H3N(CH2)6NH3}2L salts of ethylenediaminetetraacetic acid H4L to give readily soluble sodium      Na2[ZnL], potassium K2[ZnL], ammonium (NH4)2[ZnL], 2-ammonioethanol (H3NCH2CH2OH)2[ZnL], and hexamethylene-1,6-diammonium {H3N(CH2)6NH3}[ZnL] ethylenediaminetetraacetate zincates. The reaction of tetrakis(triethylammonium) salt {(C2H5)3NH}4L with Zn[ZnL] does not give the expected bis(triethylammonium) ethylenediaminetetraacetate zincate {(C2H5)3NH}2[ZnL], but gives instead mono(triethylammonium) ethylenediaminetetraacetate zincate, {(C2H5)3NH}H[ZnL]; in aqueous solution, this product generates poorly soluble zinc ethylenediaminetetraacetate H2[ZnL(H2O)]·2H2O, which was studied by X-ray diffraction (CCDC no. 2172274).

作者简介

V. Semenov

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: vvsemenov@iomc.ras.ru
Россия, Нижний Новгород

N. Zolotareva

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: vvsemenov@iomc.ras.ru
Россия, Нижний Новгород

O. Novikova

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: vvsemenov@iomc.ras.ru
Россия, Нижний Новгород

B. Petrov

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: vvsemenov@iomc.ras.ru
Россия, Нижний Новгород

N. Lazarev

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: vvsemenov@iomc.ras.ru
Россия, Нижний Новгород

R. Rumyantsev

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: vvsemenov@iomc.ras.ru
Россия, Нижний Новгород

M. Lopatin

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: vvsemenov@iomc.ras.ru
Россия, Нижний Новгород

T. Lopatina

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: vvsemenov@iomc.ras.ru
Россия, Нижний Новгород

T. Kovylina

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: vvsemenov@iomc.ras.ru
Россия, Нижний Новгород

E. Razov

Lobachevsky State University of Nizhny Novgorod, Nizhny Novgorod, Russia;
Institute of Problems of Mechanical Engineering, Russian Academy of Sciences—A Branch of the Federal Research Center, Institute of Applied Physics, Russian Academy of Sciences, Nizhny Novgorod, Russia

编辑信件的主要联系方式.
Email: vvsemenov@iomc.ras.ru
Россия, Нижний Новгород; Россия, Нижний Новгород

参考

  1. Дятлова Н.М., Темкина В.Я., Попов К.И. Комплексоны и комплексонаты металлов. М.: Химия, 1988. 544 с.
  2. Семенов В.В., Золотарева Н.В., Петров Б.И. Патент РФ 2015110362/04 (016255) // БИ. 2017. № 4.
  3. Семенов В.В., Золотарева Н.В., Новикова О.В. и др. // Изв. АН. Сер. хим. 2022. № 5. С. 980.
  4. Леонтьева М.В., Дятлова Н.М. // Коорд. химия. 1990. Т. 16. С. 823.
  5. Lakshminarayanan R. // J. Electrochem. Soc. India. 1997. V. 46. P. 45.
  6. Borowiec M., Hoffmann K., Hoffmann J. // Intern. J. Environmen. Anal. Chem. 2009. V. 89. P. 717. https://doi.org/10.1080/03067310802691672
  7. Jervis R.E., Krishnan S.S. // J. Inorg. Nucl. Chem. 1967. V. 29. P. 97. https://doi.org/10.1016/0022-1902(67)80149-0
  8. Bampidis V., Azimonti G., de Lourdes Bastos M. et al. // Eur. Food Safety Authority. 2020. V. 18. e06145. https://doi.org/10.2903/j.efsa.2020.6024
  9. Collins R.N., Merrington G., McLaughlin M.J., Knudsen C. // Environ. Toxicol. Chem. 2002. V. 21. P. 1940. https://doi.org/10.1002/etc.5620210923
  10. Soulages O.E., Acebal S.G., Grassi R.L., Vuano B.M. // Anales de la Asociacion Quimica Argentina. 1997. V. 85. P. 261.
  11. Rigaku Oxford Diffraction. CrysAlis Pro Software System. Version 1.171.41.122a. Wroclaw (Poland): Rigaku Corporation, 2021.
  12. Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. P. 3. https://doi.org/10.1107/S2053273314026370
  13. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3. https://doi.org/10.1107/S2053229614024218
  14. Фридман А.Я., Леонтьева М.В., Дятлова Н.М. // Коорд. химия. 1986. Т. 12. С. 736.
  15. Mizuta T., Wang J., Miyoshi K. // Inorg. Chim. Acta. 1995. V. 230. P. 119. https://doi.org/10.1016/0020-1693(94)04311-I
  16. Зефиров Ю.В., Зоркий П.М. // Успехи химии. 1995. Т. 64. С. 446 (Zefirov Yu.V., Zorky P.M. // Russ. Chem. Rev. 1995. V. 64. P. 415). https://doi.org/10.1070/RC1995v064n05ABEH000157

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版权所有 © В.В. Семенов, Н.В. Золотарева, О.В. Новикова, Б.И. Петров, Н.М. Лазарев, Р.В. Румянцев, М.А. Лопатин, Т.И. Лопатина, Т.А. Ковылина, Е.Н. Разов, 2023