2D Coordination Polymers of Zn(II) with Diethylmalonic Acid Dianions and 4,4´-bipyridine: Synthesis and Structures

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Abstract

Two new coordination compounds of zinc(II) with diethylmalonic acid anions (Et2mal2–) and 4,4´-bipyridine (4,4´-bipy) are synthesized: {[Zn(H2O)(4,4´-bipy)(Et2mal)]· 0.5C2H5OH·1.5H2O}n (I) and {[Zn4(H2O)2(4,4´-bipy)3(Et2mal)4]·6H2O}n (II). According to the XRD data (CIF files CCDC nos. 2323336 (I) and 2323337 (II)), both compounds are 2D polymers with the sql and bey topology, respectively. The choice of the initial zinc salt and solvent predetermines the compositions and structures of the polymers under similar synthesis conditions.

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About the authors

A. S. Chistyakov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: ezorinatikhonova@gmail.com
Russian Federation, Moscow

E. N. Zorina-Tikhonova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: ezorinatikhonova@gmail.com
Russian Federation, Moscow

A. V. Vologzhanina

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: ezorinatikhonova@gmail.com
Russian Federation, Moscow

M. A. Kiskin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: ezorinatikhonova@gmail.com
Russian Federation, Moscow

I. L. Eremenko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: ezorinatikhonova@gmail.com
Russian Federation, Moscow; Moscow

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2. Fig. 1. Independent part of the cell I (a) and II (b) in the representation of atoms by thermal ellipsoids (depicted with probability p = 50%)

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3. Fig. 2. Fragments of layers of composition [Zn(H2O)(4,4´-bipy)(Et2mal)] and [Zn4(H2O)2(4,4´-bipy)3(Et2mal)4] in I (a) and II (c) and meshes obtained by simplifying these structures with sql (b) and bey (d) topologies, respectively

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