Palladium Complexes of Pyrimidine-2-thiones: Synthesis, Structures, and Properties

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

Complexes [PdL2Cl2] (I) and [PdL2Вr2] (II) (L is 5-acetyl-6-methyl-4-(3-nitrophenyl)-1,2,3,4-tetrahydropyrimidine-2-thione) are synthesized and characterized by spectral methods (1Н, 13С NMR and IR spectroscopy). The crystal structure of complex I is determined (CIF file ССDС no. 2233053) in which the palladium atom is coordinated by two halide ions and two sulfur atoms of two ligands L in a distorted square planar geometry. The catalytic activity of the synthesized palladium(II) complexes in the model epoxidation of allyl alcohol is estimated in comparison with the catalytic activity of the corresponding palladium halides and titanium-containing zeolite TS-1.

Толық мәтін

Рұқсат жабық

Авторлар туралы

A. Kuzovlev

Moscow State University; Tyumen State University

Хат алмасуға жауапты Автор.
Email: a.s.kuzovlev@gmail.com
Ресей, Moscow; Tyumen

N. Gordeeva

Russian Technological University (MIREA)

Email: a.s.kuzovlev@gmail.com
Ресей, Moscow

Zh. Pastukhova

Russian Technological University (MIREA)

Email: a.s.kuzovlev@gmail.com
Ресей, Moscow

V. Chernyshev

Moscow State University; Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: a.s.kuzovlev@gmail.com
Ресей, Moscow; Moscow

G. Buzanov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: a.s.kuzovlev@gmail.com
Ресей, Moscow

S. Dunaev

Moscow State University

Email: a.s.kuzovlev@gmail.com
Ресей, Moscow

L. Bruk

Russian Technological University (MIREA)

Email: a.s.kuzovlev@gmail.com
Ресей, Moscow

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Әрекет
1. JATS XML
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2. Scheme 1.

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3. Fig. 1. Molecular structure of complex I, showing the numbering of the non-hydrogen atoms and the atomic displacement spheres of 50% probability. The Pd(1) atom is at the centre of the inversion, the unnumbered atoms are linked to the numbered symmetry operations i - x, 1 - y, 2 - z.

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4. Fig. 2. Experimental diffractograms of II (curve 1) and I (curve 2).

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5. Scheme 2.

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6. Fig. 3. Kinetic curves of reagent consumption (AC - allyl alcohol, SP - hydrogen peroxide) and target product formation (GD - glycidol) during the epoxidation process using TS-1 as a catalyst.

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