Polyampholite–Metal Complexes for Catalytic Processes
- Authors: Lipin V.A.1, Poshvina T.A.1, Fedorova K.A.1, Fadin A.F.1, Maltseva N.V.1, Vishnevskaya T.A.1
- 
							Affiliations: 
							- Saint Petersburg State Institute of Technology
 
- Issue: Vol 65, No 3 (2023)
- Pages: 230-240
- Section: КОМПОЗИТЫ
- URL: https://cardiosomatics.ru/2308-1139/article/view/650890
- DOI: https://doi.org/10.31857/S2308113923700493
- EDN: https://elibrary.ru/GZPSYK
- ID: 650890
Cite item
Abstract
Polyampholyte–metal complexes based on polyacrylic acid; the aliphatic diamines ethylenediamine, 1,3-diaminopropane, and 1,4-diaminobutane; and Cu2+ was obtained by reacting aqueous solutions of polyampholytes and CuSO4. Using the method of simultaneous thermal analysis, it was found that the thermal degradation of the complexes occurs in three steps. The activation energy of thermal degradation of the polyampholyte–metal complexes is 22–99 kJ/mol. It was established by X-ray diffraction analysis that the products of thermal degradation of polyampholyte–metal complexes are heterogeneous systems composed of CuO and Cu2O phases, while catalysts based on them are heterogeneous systems consisting of Al2O3 and CuO phases. The size distribution of catalyst pores showed that the volume of pores with a diameter of less than 773 nm was 0.80–0.83 cm3/g, the specific surface area was 349–351 m2/g, and the predominant equivalent pore diameter was 6.2–6.3 nm. The mechanical crushing strength of catalyst pellets was found to be 7.1–7.3 MPa. In the process of CO oxidation to CO2, the catalyst began to exhibit its activity at 180–187°C; the complete conversion of CO in the oxidation reaction was achieved at 280–286°C. The performance of the obtained catalysts was 2.7–2.8 times higher than that of a reference sample.
About the authors
V. A. Lipin
Saint Petersburg State Institute of Technology
														Email: ksuchayka@mail.ru
				                					                																			                												                								190013, St. Petersburg, Russia						
T. A. Poshvina
Saint Petersburg State Institute of Technology
														Email: ksuchayka@mail.ru
				                					                																			                												                								190013, St. Petersburg, Russia						
K. A. Fedorova
Saint Petersburg State Institute of Technology
														Email: ksuchayka@mail.ru
				                					                																			                												                								190013, St. Petersburg, Russia						
A. F. Fadin
Saint Petersburg State Institute of Technology
														Email: ksuchayka@mail.ru
				                					                																			                												                								190013, St. Petersburg, Russia						
N. V. Maltseva
Saint Petersburg State Institute of Technology
														Email: ksuchayka@mail.ru
				                					                																			                												                								190013, St. Petersburg, Russia						
T. A. Vishnevskaya
Saint Petersburg State Institute of Technology
							Author for correspondence.
							Email: ksuchayka@mail.ru
				                					                																			                												                								190013, St. Petersburg, Russia						
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